Bi3(PO4)O3, the Simplest Bismuth(III) Oxophosphate: Synthesis, IR Spectroscopy, Crystal Structure, and Structural Complexity

被引：7

作者：

Aksenov, Sergey M. ^{[1
]}

Yamnova, Natalia A. ^{[3
]}

Borovikova, Elena Yu ^{[3
]}

Volkov, Anatoly S. ^{[3
]}

Ksenofontov, Dmitry A. ^{[3
]}

Dimitrova, Olga, V ^{[3
]}

Gurbanova, Olga A. ^{[3
]}

Deyneko, Dina, V ^{[4
]}

Dal Bo, Fabrice ^{[1
]}

Burns, Peter C. ^{[1
,2
]}

机构：

[1] Univ Notre Dame, Dept Civil & Environm Engn & Earth Sci, Notre Dame, IN 46556 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[3] Lomonosov Moscow State Univ, Dept Crystallog & Crystal Chem, Moscow 119991, Russia

[4] Lomonosov Moscow State Univ, Dept Chem Technol, Moscow 119991, Russia

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

BOND-VALENCE PARAMETERS; OXIDE-ION CONDUCTORS; 1D SINGLE-CHAIN; TOPOLOGICAL COMPLEXITY; BI3+/M2+ OXYPHOSPHATE; CONTINUOUS SERIES; 2D PLANES; CATIONS; PHASES; SYSTEM;

D O I：

10.1021/acs.inorgchem.8b01195

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bismuth(III) oxophosphate Bi-3(PO4)O-3 was obtained by hydrothermal synthesis. The unit cell has a = 5.6840(6) angstrom, b = 7.0334(7) angstrom, c = 9.1578(9) angstrom, alpha = 78.958(2)degrees, beta = 77.858(2)degrees, gamma = 68.992(2)degrees, V = 331.41(6) angstrom(3) , space group P (1) over bar, and Z = 2. The crystal chemical formula that reflects the presence of oxo-centered-tetrahedra and triangles is (2D)[(OO2Bi3)-O-III-Bi-IV] (PO4). The crystal structure contains [O3Bi3](3)+(infinity infinity)-heteropolyhedral corrugated layers parallel to (001), which alternate along [001] with isolated (PO4) tetrahedra. The structural complexity parameters are v = 22 atoms, I-G = 3.459 bits/atoms, and I-G,I-total = 76.107 bits/unit cell, and thus Bi-3(PO4)O-3 is the simplest pure bismuth(III) oxophosphate.

引用

页码：6799 / 6802

页数：4

共 40 条

[1] Synthesis, crystal structure, vibrational spectroscopy and expected magnetic properties of a new bismuth nickel phosphate Ni(BiO)2(PO4)(OH) with a namibite-type structure [J].

Aksenov, Sergey M. ;

Mironov, Vladimir S. ;

Borovikova, Elena Yu. ;

Yamnova, Natalia A. ;

Gurbanova, Olga A. ;

Volkov, Anatoly S. ;

Dimitrova, Olga V. ;

Deyneko, Dina V. .

SOLID STATE SCIENCES, 2017, 63 :16-22

[2] Labile Degree of Disorder in Bismuth-Oxophosphate Compounds: Illustration through Three New Structural Types [J].

Aliev, A. ;

Endara, D. ;

Huve, M. ;

Colmont, M. ;

Roussel, P. ;

Delevoye, L. ;

Tran, T. T. ;

Halasyamani, P. S. ;

Mentre, O. .

INORGANIC CHEMISTRY, 2014, 53 (02) :861-871

[3] Crystal structures and polymorphism in compounds Bi6+xT1-xP2O15+y, T = first row transition metals and Pb [J].

Arumugam, Nachiappan ;

Lynch, Vincent ;

Steinfink, Hugo .

JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (09) :2313-2317

[4] Applied Topological Analysis of Crystal Structures with the Program Package ToposPro [J].

Blatov, Vladislav A. ;

Shevchenko, Alexander P. ;

Proserpio, Davide M. .

CRYSTAL GROWTH & DESIGN, 2014, 14 (07) :3576-3586

[5] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[6] INVESTIGATION OF ETHENE SELECTIVITY IN THE METHANE COUPLING REACTION ON CHLORINE-CONTAINING CATALYSTS [J].

BURCH, R ;

CHALKER, S ;

LOADER, P ;

THOMAS, JM ;

UEDA, W .

APPLIED CATALYSIS A-GENERAL, 1992, 82 (01) :77-90

[7] Bi3+/M2+ oxyphosphate:: A continuous series of polycationic species from the 1D single chain to the 2D planes.: Part 2:: Crystal structure of three original structural types showing a combination of new ribbonlike polycations [J].

Colmont, Marie ;

Huve, Marielle ;

Mentre, Olivier .

INORGANIC CHEMISTRY, 2006, 45 (17) :6612-6621

[8] Bi2O3-CuO-P2O5 system: Two novel compounds built from the intergrowths oxocentered polycationic 1D-ribbons [J].

Colmont, Marie ;

Endara, Diana ;

Aliev, Almaz ;

Terryn, Christine ;

Huve, Marielle ;

Mentre, Olivier .

JOURNAL OF SOLID STATE CHEMISTRY, 2013, 203 :266-272

[9] Crystal structures of the ionic conductors Bi46M8O89 (M = P, V) related to the fluorite-type structure [J].

Darriet, J ;

Launay, JC ;

Zúniga, FJ .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (06) :1753-1764

[10] Novel Tailormade Bi4MO4(PO4)2 Structural Type (M = Mg, Zn) [J].

Endara, Diana ;

Colmont, Marie ;

Huve, Marielle ;

Tricot, Gregory ;

Carpentier, Laurent ;

Mentre, Olivier .

INORGANIC CHEMISTRY, 2012, 51 (08) :4438-4447

← 1 2 3 4 →