Bi3(PO4)O3, the Simplest Bismuth(III) Oxophosphate: Synthesis, IR Spectroscopy, Crystal Structure, and Structural Complexity

被引：7

作者：

Aksenov, Sergey M. ^{[1
]}

Yamnova, Natalia A. ^{[3
]}

Borovikova, Elena Yu ^{[3
]}

Volkov, Anatoly S. ^{[3
]}

Ksenofontov, Dmitry A. ^{[3
]}

Dimitrova, Olga, V ^{[3
]}

Gurbanova, Olga A. ^{[3
]}

Deyneko, Dina, V ^{[4
]}

Dal Bo, Fabrice ^{[1
]}

Burns, Peter C. ^{[1
,2
]}

机构：

[1] Univ Notre Dame, Dept Civil & Environm Engn & Earth Sci, Notre Dame, IN 46556 USA

[2] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[3] Lomonosov Moscow State Univ, Dept Crystallog & Crystal Chem, Moscow 119991, Russia

[4] Lomonosov Moscow State Univ, Dept Chem Technol, Moscow 119991, Russia

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

BOND-VALENCE PARAMETERS; OXIDE-ION CONDUCTORS; 1D SINGLE-CHAIN; TOPOLOGICAL COMPLEXITY; BI3+/M2+ OXYPHOSPHATE; CONTINUOUS SERIES; 2D PLANES; CATIONS; PHASES; SYSTEM;

D O I：

10.1021/acs.inorgchem.8b01195

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bismuth(III) oxophosphate Bi-3(PO4)O-3 was obtained by hydrothermal synthesis. The unit cell has a = 5.6840(6) angstrom, b = 7.0334(7) angstrom, c = 9.1578(9) angstrom, alpha = 78.958(2)degrees, beta = 77.858(2)degrees, gamma = 68.992(2)degrees, V = 331.41(6) angstrom(3) , space group P (1) over bar, and Z = 2. The crystal chemical formula that reflects the presence of oxo-centered-tetrahedra and triangles is (2D)[(OO2Bi3)-O-III-Bi-IV] (PO4). The crystal structure contains [O3Bi3](3)+(infinity infinity)-heteropolyhedral corrugated layers parallel to (001), which alternate along [001] with isolated (PO4) tetrahedra. The structural complexity parameters are v = 22 atoms, I-G = 3.459 bits/atoms, and I-G,I-total = 76.107 bits/unit cell, and thus Bi-3(PO4)O-3 is the simplest pure bismuth(III) oxophosphate.

引用

页码：6799 / 6802

页数：4

共 40 条

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