Egg white derived carbon materials as an efficient sulfur host for high-performance lithium-sulfur batteries and its electrochemical properties

被引:11
作者
Reddy, B. S. [1 ,2 ]
Premasudha, M. [1 ,2 ]
Oh, Kwang-Moon [1 ,2 ]
Reddy, N. S. [3 ]
Ahn, Jou-Hyeon [1 ,2 ,4 ]
Cho, Kwon-Koo [1 ,2 ]
机构
[1] Gyeongsang Natl Univ, Dept Mat Engn & Convergence Technol, 501 Jinju Daero, Jinju 52828, South Korea
[2] Gyeongsang Natl Univ, Res Inst Green Energy Convergence Technol, 501 Jinju Daero, Jinju 52828, South Korea
[3] Gyeongsang Natl Univ, Engn Res Inst, Sch Mat Sci & Engn, 501 Jinju Daero, Jinju 52828, South Korea
[4] Gyeongsang Natl Univ, Dept Chem Engn, 501 Jinju Daero, Jinju 52828, South Korea
基金
新加坡国家研究基金会;
关键词
Cheese-like carbon; Egg white; Sulfur; Lithium-sulfur batteries; HIERARCHICAL POROUS CARBON; SEPARATOR; CATHODES; MATRIX; SHELL;
D O I
10.1016/j.materresbull.2021.111310
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lithium-sulfur (Li-S) batteries are attractive and prominent power sources due to high theoretical capacity and the availability of sulfur at a low price. However, sulfur has limitations such as the formation of polysulfides and low conductivity. To overcome these problems, we prepared a cheese-like carbon (CLC) using a simple annealing process from an egg white. The as-prepared carbon material contains NaCl and KCl compounds. The CLC with nanoholes were formed after cleaning with distilled water and ethanol several times. The prepared CLC had a strong polysulfide capturing ability, high conductivity, a large surface area, and high catalytic activity. To prepare the CLC/S composite, sulfur was added by the melt diffusion method. CLC/S cathode material exhibited a high initial capacity of nearly 1420 mA h g(-1) at 0.1 C and excellent rate capability with a low capacity-fading rate. The present work revealed that CLC/S cathodes are potential candidate cathodes for Li-S batteries.
引用
收藏
页数:6
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