Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

被引：693

作者：

Chakraborty, Gouri ^{[1
]}

Park, In-Hyeok ^{[2
]}

Medishetty, Raghavender ^{[3
]}

Vittal, Jagadese J. ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] Chungnam Natl Univ, Grad Sch Analyt Sci & Technol GRAST, Daejeon 34134, South Korea

[3] IIT Bhilai, Dept Chem, Raipur 492015, Madhya Pradesh, India

来源：

CHEMICAL REVIEWS | 2021年 / 121卷 / 07期

关键词：

2D COORDINATION POLYMERS; SINGLE-CRYSTAL TRANSFORMATION; SLOW MAGNETIC-RELAXATION; SPIN-CROSSOVER BEHAVIOR; SECONDARY BUILDING UNITS; 2+2 CYCLOADDITION REACTION; INTERPENETRATING MOLECULAR LADDERS; EFFICIENT HETEROGENEOUS CATALYST; LIGANDS TOPOLOGICAL DIVERSITY; LONG FLEXIBLE BIS(IMIDAZOLE);

D O I：

10.1021/acs.chemrev.0c01049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties and applications, including gas and guest sorption, storage and separation of gases and small molecules, catalysis, luminescence, sensing, magnetism, and energy storage and conversion. Among MOFs, two-dimensional (2D) compounds are also known as 2D CPs or 2D MOFs. Since the discovery of graphene in 2004, 2D materials have also been widely studied. Several 2D MOFs are suitable for exfoliation as ultrathin nanosheets similar to graphene and other 2D materials, making these layered structures useful and unique for various technological applications. Furthermore, these layered structures have fascinating topological networks and entanglements. This review provides an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.

引用

页码：3751 / 3891

页数：141

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