Non-isothermal kinetics of spin crossover

被引：8
|
作者：
Bushuev, Mark B. [1 ,2 ]
Nikolaenkova, Elena B. [3 ]
Krivopalov, Viktor P. [3 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, 9 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2017年 / 19卷 / 26期
基金：
俄罗斯基础研究基金会;
关键词：
LARGE THERMAL HYSTERESIS; IRON(II) COMPLEXES; ACTIVATION-ENERGY; TRANSITION; STATE; INTERPLAY; TEMPERATURE; LIGANDS;
D O I：
10.1039/c7cp03442c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.
引用
收藏
页码：16955 / 16959
页数：5
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