Acylation of alcohols with acetic anhydride catalyzed by TaCl5:: Some implications in kinetic resolution

被引：181

作者：

Chandrasekhar, S ^{[1
]}

Ramachander, T ^{[1
]}

Takhi, M ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(98)00465-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

TaCl5 and TaCl5-Silica gel have been effectively used as Lewis acid catalysts for acetylation of alcohols. Also TaCl3-Chiral ligands have been used for kinetic resolution of 2 degrees alcohols albeit in low ees. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3263 / 3266

页数：4

共 13 条

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