Evidence of structural variability among synthetic and biogenic vaterite

被引:24
作者
Falini, Giuseppe [1 ]
Fermani, Simona [1 ]
Reggi, Michela [1 ]
Dzakula, Branka Njegic [2 ]
Kralj, Damir [2 ]
机构
[1] Univ Bologna, Alma Mater Studiorum, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] Rudjer Boskovic Inst, Lab Precipitat Proc, HR-10002 Zagreb, Croatia
关键词
AMORPHOUS CALCIUM-CARBONATE; CRYSTALLIZATION; TRANSFORMATION; ARAGONITE; DISORDER; CACO3; PHASE;
D O I
10.1039/c4cc05054a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Recently, the results of experimental and theoretical investigations have revealed that, in vaterite, two or even more crystalline structures coexist. In this communication we report evidence of diverse vaterite structures in biogenic samples of different origin. In addition, it is shown that the synthetic vaterite precipitated in the presence of poly-L-aspartate has structures similar to those of biogenic samples.
引用
收藏
页码:15370 / 15373
页数:4
相关论文
共 37 条
[31]   Biominerals [J].
Skinner, HCW .
MINERALOGICAL MAGAZINE, 2005, 69 (05) :621-641
[32]   Atomic order of aragonite crystals formed by mollusks [J].
Suzuki, Michio ;
Dauphin, Yannicke ;
Addadi, Lia ;
Weiner, Steve .
CRYSTENGCOMM, 2011, 13 (22) :6780-6786
[33]   Pure Protein Microspheres by Calcium Carbonate Templating [J].
Volodkin, Dmitry V. ;
von Klitzing, Regine ;
Moehwald, Helmuth .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (48) :9258-9261
[34]   Amorphous, nanocrystalline and crystalline calcium carbonates in biological materials [J].
Wehrmeister, U. ;
Jacob, D. E. ;
Soldati, A. L. ;
Loges, N. ;
Haeger, T. ;
Hofmeister, W. .
JOURNAL OF RAMAN SPECTROSCOPY, 2011, 42 (05) :926-935
[35]   Thermophysical investigations of the polymorphous phases of calcium carbonate [J].
Wolf, G ;
Günther, C .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 65 (03) :687-698
[36]   Synthesis of dispersive CaCO3 in the presence of MgO2 [J].
Xiang, L. ;
Wen, Y. ;
Wang, Q. ;
Jin, Y. .
MATERIALS CHEMISTRY AND PHYSICS, 2006, 98 (2-3) :236-240
[37]   Templating Assembly of Multifunctional Hybrid Colloidal Spheres [J].
Yan, Xuehai ;
Li, Junbai ;
Moehwald, Helmuth .
ADVANCED MATERIALS, 2012, 24 (20) :2663-2667