A chirped pulse Fourier transform microwave spectrometer with multi-antenna detection

被引:13
作者
Duerden, Amanda [1 ]
Marshall, Frank E. [1 ]
Moon, Nicole [1 ]
Swanson, Christian [1 ]
Donnell, Kristen M. [2 ]
Grubbs, G. S., II [1 ]
机构
[1] Missouri Univ Sci & Technol, Dept Chem, 400 W 11th St, Rolla, MO 65409 USA
[2] Dept Elect & Comp Engn, 301 W 16th St, Rolla, MO 65409 USA
基金
美国国家科学基金会;
关键词
Rotational spectroscopy; CP-FTMW detection; MAD-CP-FTMW; MAD-Chirp; ROTATIONAL SPECTROSCOPY; CHIRAL MOLECULES; FAST-PASSAGE; SPECTRA;
D O I
10.1016/j.jms.2020.111396
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The construction of a new chirped pulse Fourier transform microwave (CP-FTMW) spectrometer with multiple-antenna detection (MAD) is reported. The instrument design and execution represent a completely new approach to possibly increasing sensitivity in CP-FTMW spectroscopy as it does not involve increased sampling, power, or passes of microwaves with the molecular sample. This is particularly advantageous for experiments where only one sampling point is available. The MAD-CP-FTMW or ?MAD Chirp? is demonstrated on both linear molecule carbonyl sulfide (OCS) and asymmetric-top molecule 1,3-difluorobenzene (DFBZ) with detection points at the broadcast antenna as well as in the quadrature to the traditional receiving antenna. Signal-to-noise comparisons with each sample at each detection point have been made and are reported. Experiments demonstrating the signals detected in these new positions are molecular and not an artifact of a reflection are reported. Although this represents a first step to a possible new approach to addressing CP-FTMW sensitivity, no sensitivity increase based on this method is currently reported. ? 2020 Elsevier Inc. All rights reserved.
引用
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页数:6
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