Defect formation in graphene during low-energy ion bombardment

被引:67
作者
Ahlberg, P. [1 ]
Johansson, F. O. L. [2 ]
Zhang, Z. -B. [1 ]
Jansson, U. [3 ]
Zhang, S. -L. [1 ]
Lindblad, A. [2 ]
Nyberg, T. [1 ]
机构
[1] Uppsala Univ, Angstrom Lab, Div Solid State Elect, Box 534, SE-75121 Uppsala, Sweden
[2] Uppsala Univ, Dept Phys & Astron Mol & Condensed Matter Phys, Box 516, SE-75120 Uppsala, Sweden
[3] Uppsala Univ, Dept Chem, Inorgan Chem, Box 538, SE-75121 Uppsala, Sweden
基金
瑞典研究理事会;
关键词
RAMAN-SPECTROSCOPY;
D O I
10.1063/1.4945587
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This letter reports on a systematic investigation of sputter induced damage in graphene caused by low energy Ar+ ion bombardment. The integral numbers of ions per area (dose) as well as their energies are varied in the range of a few eV's up to 200 eV. The defects in the graphene are correlated to the dose/energy and different mechanisms for the defect formation are presented. The energetic bombardment associated with the conventional sputter deposition process is typically in the investigated energy range. However, during sputter deposition on graphene, the energetic particle bombardment potentially disrupts the crystallinity and consequently deteriorates its properties. One purpose with the present study is therefore to demonstrate the limits and possibilities with sputter deposition of thin films on graphene and to identify energy levels necessary to obtain defect free graphene during the sputter deposition process. Another purpose is to disclose the fundamental mechanisms responsible for defect formation in graphene for the studied energy range. (C) 2016 Author(s).
引用
收藏
页数:6
相关论文
共 22 条
[1]  
Ado J., 2010, J PHYS CONDENS MATT, V22
[2]  
Banhart F, 2011, ACS NANO, V5, P26, DOI [10.1021/nn102598m, 10.1016/B978-0-08-102053-1.00005-3]
[3]   Ultrahigh electron mobility in suspended graphene [J].
Bolotin, K. I. ;
Sikes, K. J. ;
Jiang, Z. ;
Klima, M. ;
Fudenberg, G. ;
Hone, J. ;
Kim, P. ;
Stormer, H. L. .
SOLID STATE COMMUNICATIONS, 2008, 146 (9-10) :351-355
[4]   Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies [J].
Cancado, L. G. ;
Jorio, A. ;
Martins Ferreira, E. H. ;
Stavale, F. ;
Achete, C. A. ;
Capaz, R. B. ;
Moutinho, M. V. O. ;
Lombardo, A. ;
Kulmala, T. S. ;
Ferrari, A. C. .
NANO LETTERS, 2011, 11 (08) :3190-3196
[5]   Low-damage high-throughput grazing-angle sputter deposition on graphene [J].
Chen, C. -T. ;
Casu, E. A. ;
Gajek, M. ;
Raoux, S. .
APPLIED PHYSICS LETTERS, 2013, 103 (03)
[6]   Ion irradiation and defect formation in single layer graphene [J].
Compagnini, Giuseppe ;
Giannazzo, Filippo ;
Sonde, Sushant ;
Raineri, Vito ;
Rimini, Emanuele .
CARBON, 2009, 47 (14) :3201-3207
[7]   Interpretation of Raman spectra of disordered and amorphous carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2000, 61 (20) :14095-14107
[8]   Resonant Raman spectroscopy of disordered, amorphous, and diamondlike carbon [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2001, 64 (07)
[9]   Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems [J].
Ferrari, Andrea C. ;
Bonaccorso, Francesco ;
Fal'ko, Vladimir ;
Novoselov, Konstantin S. ;
Roche, Stephan ;
Boggild, Peter ;
Borini, Stefano ;
Koppens, Frank H. L. ;
Palermo, Vincenzo ;
Pugno, Nicola ;
Garrido, Jose A. ;
Sordan, Roman ;
Bianco, Alberto ;
Ballerini, Laura ;
Prato, Maurizio ;
Lidorikis, Elefterios ;
Kivioja, Jani ;
Marinelli, Claudio ;
Ryhaenen, Tapani ;
Morpurgo, Alberto ;
Coleman, Jonathan N. ;
Nicolosi, Valeria ;
Colombo, Luigi ;
Fert, Albert ;
Garcia-Hernandez, Mar ;
Bachtold, Adrian ;
Schneider, Gregory F. ;
Guinea, Francisco ;
Dekker, Cees ;
Barbone, Matteo ;
Sun, Zhipei ;
Galiotis, Costas ;
Grigorenko, Alexander N. ;
Konstantatos, Gerasimos ;
Kis, Andras ;
Katsnelson, Mikhail ;
Vandersypen, Lieven ;
Loiseau, Annick ;
Morandi, Vittorio ;
Neumaier, Daniel ;
Treossi, Emanuele ;
Pellegrini, Vittorio ;
Polini, Marco ;
Tredicucci, Alessandro ;
Williams, Gareth M. ;
Hong, Byung Hee ;
Ahn, Jong-Hyun ;
Kim, Jong Min ;
Zirath, Herbert ;
van Wees, Bart J. .
NANOSCALE, 2015, 7 (11) :4598-4810
[10]   Raman spectroscopy as a versatile tool for studying the properties of graphene [J].
Ferrari, Andrea C. ;
Basko, Denis M. .
NATURE NANOTECHNOLOGY, 2013, 8 (04) :235-246