POLY(SODIUM-10-UNDECYLENATE) AS PSEUDO-STATIONARY PHASE IN THE SEPARATION AND QUANTIFICATION OF POLYAROMATIC HYDROCARBONS BY MICELLAR ELECTROKINETIC CHROMATOGRAPHY

被引：0

作者：

Pereira, Eduardo D. ^{[1
]}

Rivas, Bernabe L. ^{[2
]}

Peric, Ivan ^{[1
]}

Gallegos, Paola ^{[1
]}

Figueroa, Valeska ^{[1
]}

机构：

[1] Univ Concepcion, Fac Chem, Analyt & Inorgan Chem Dept, Concepcion, Chile

[2] Univ Concepcion, Fac Chem, Polymer Dept, Concepcion, Chile

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2010年 / 55卷 / 01期

关键词：

PSEUDOSTATIONARY PHASES; POLYMERS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work we reported the synthesis of different molar mass fraction of poly(sodium-10-undecylenate) (PSU), and its subsequent utilization as pseudostationary phase in the separation of a mix of 4 polyaromatic hydrocarbons (PAHs); naphthalene (NAPH), fluorene (FLU), phenantrene (PHEN) and pyrene (PYR). Concentration and molar mass fraction of PSU were the main variable studied. The analytical parameters; efficiency (N), selectivity (a), and resolution (R,) were calculated to assess the separation capacity. The best conditions for the separation were achieved using a buffer composed by 12.5 mM of each sodium borate and sodium hydrogen phosphate, yielding pH 9.2 in ACN/H2O (40/60) solvent, using PSU of molar mass fraction 30-50 kDa in concentration of 0.25 g 100 mL(-1). The applied voltage was 25 kV. Finally, Limit of Detection (LOD) and Limit of Quantification (LOQ) for 4 PAHs were calculated from the calibration curves in optimal separation conditions.

引用

页码：31 / 34

页数：4

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