Conversion of carbonyl compounds to alkynes: general overview and recent developments

被引：125

作者：

Habrant, Damien ^{[1
]}

Rauhala, Vesa ^{[1
]}

Koskinen, Ari M. P. ^{[1
]}

机构：

[1] Aalto Univ, Sch Sci & Technol, Organ Chem Lab, FIN-00076 Aalto, Finland

来源：

CHEMICAL SOCIETY REVIEWS | 2010年 / 39卷 / 06期

关键词：

BESTMANN-OHIRA REAGENT; ONE-POT CONVERSION; TERMINAL ALKYNES; DIMETHYL (DIAZOMETHYL)PHOSPHONATE; EMMONS MODIFICATION; ACTIVATED ALCOHOLS; MANGANESE-DIOXIDE; ALDEHYDES; KETONES; CORE;

D O I：

10.1039/b915418c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of alkynes from carbonyl compounds via a one-carbon homologation has become a very useful pathway for the synthesis of acetylenic compounds, both internal and terminal. This tutorial review provides an overview of the different methods available for this transformation, including their scope and limitations, recent developments and applications in total syntheses.

引用

页码：2007 / 2017

页数：11

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