Preparation and Photoelectrochemical Performance of Visible-Light Active Agl/TiO2-NTs Composite with Rich β-Agl

被引:23
作者
Wang, Qi [1 ,2 ,3 ]
Shi, Xiaodong [1 ]
Liu, Enqin [1 ]
Xu, Jianjia [1 ]
Crittenden, John C. [2 ,3 ]
Zhang, Yi [1 ]
Cong, Yanqing [1 ]
机构
[1] Zhejiang Gongshang Univ, Sch Environm Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R China
[2] Georgia Inst Technol, Brook Byer Inst Sustainable Syst, Atlanta, GA 30332 USA
[3] Georgia Inst Technol, Sch Civil & Environm Engn, Atlanta, GA 30332 USA
基金
中国国家自然科学基金;
关键词
HETEROGENEOUS PHOTOCATALYTIC REDUCTION; HEXAVALENT CHROMIUM; WASTE-WATER; NANOTUBE ARRAYS; AMORPHOUS TIO2; DEGRADATION; CR(VI); AGI/TIO2; IRRADIATION; REMOVAL;
D O I
10.1021/acs.iecr.6b00883
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
AgI sensitized TiO2 nanotube arrays (AgI/TiO2-NTs) with adjustable beta/gamma ratio of AgI were prepared by a simple dissolution-precipitation-calcination process. The samples were characterized by various techniques, including X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, ultraviolet-visible diffuse reflectance spectroscopy, linear sweep voltammetry, electrochemical impedance spectroscopy, and Mott-Schottky plots. We found that calcination temperature (100-500 degrees C) had significant effect on regulating the phase of AgI. After calcination at 350 degrees C, the highest beta/gamma ratio of AgI was achieved. Moreover, greatly enhanced photocurrent response and reduced charge transfer resistance were also observed, which together led to easier generation and separation of photogenerated electron-hole pairs. Thus, for the reduction of Cr(VI) under visible light, significantly enhanced photoelectrocatalytic (PEC) performance was observed using AgI/TiO2-NTs calcined at 350 degrees C (denoted as AgI/TiO2-NTs350) as photoanode and Ti foil as cathode, respectively. At very low content of AgI (1.25%), the estimated k(Cr(VI)) (0.0155 min(-1)) was nearly 5 times that of pure TiO2-NTs350.
引用
收藏
页码:4897 / 4904
页数:8
相关论文
共 45 条
[1]   Electrochemical degradation of chloramphenicol with a novel Al doped PbO2 electrode: Performance, kinetics and degradation mechanism [J].
Chen, Jianmeng ;
Xia, Yijing ;
Dai, Qizhou .
ELECTROCHIMICA ACTA, 2015, 165 :277-287
[2]   Electronic Structures and Photocatalysis Properties under Visible Irradiation of F-doped TiO2 Nanotube Arrays [J].
Chen Xiu-Qin ;
Zhang Xing-Wang ;
Lei Le-Cheng .
JOURNAL OF INORGANIC MATERIALS, 2011, 26 (04) :369-374
[3]   Heterogeneous photocatalytic reduction of Cr(VI) in UV-irradiated titania suspensions: Effect of protons, ammonium ions, and other interfacial aspects [J].
Chenthamarakshan, CR ;
Rajeshwar, K .
LANGMUIR, 2000, 16 (06) :2715-2721
[4]   Synthesis of α-Fe2O3/TiO2 nanotube arrays for photoelectro-Fenton degradation of phenol [J].
Cong, Yanqing ;
Li, Zhe ;
Zhang, Yi ;
Wang, Qi ;
Xu, Qian .
CHEMICAL ENGINEERING JOURNAL, 2012, 191 :356-363
[5]   Hexavalent chromium reduction in contaminated soil: A comparison between ferrous sulphate and nanoscale zero-valent iron [J].
Di Palma, L. ;
Gueye, M. T. ;
Petrucci, E. .
JOURNAL OF HAZARDOUS MATERIALS, 2015, 281 :70-76
[6]   Controllable synthesis of hexagon-shaped β-AgI nanoplates in reactable ionic liquid and their photocatalytic activity [J].
Feng, Sheng ;
Xu, Hui ;
Liu, Ling ;
Song, Yanhua ;
Li, Huaming ;
Xu, Yuanguo ;
Xia, Jiexiang ;
Yin, Sheng ;
Yan, Jia .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 410 :23-30
[7]   Highly Efficient Photoelectrocatalytic Reduction of Hexavalent Chromium based on the Cascade Energy Transfer towards Using no Semiconducting Photocatalysts [J].
Feng, Xiang ;
Shang, Jing ;
Zhu, Tong .
ELECTROCHIMICA ACTA, 2016, 188 :752-756
[8]   Electrochemical enhancement of solar photocatalysis: Degradation of endocrine disruptor bisphenol-A on Ti/TiO2 films [J].
Frontistis, Zacharias ;
Daskalaki, Vasileia M. ;
Katsaounis, Alexandros ;
Poulios, Ioannis ;
Mantzavinos, Dionissios .
WATER RESEARCH, 2011, 45 (09) :2996-3004
[9]   Solar photoelectrocatalytic degradation of Acid Orange 7 azo dye using a highly stable TiO2 photoanode synthesized by atmospheric plasma spray [J].
Garcia-Segura, Sergi ;
Dosta, Sergi ;
Guilemany, Josep M. ;
Brillas, Enric .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 132 :142-150
[10]   Influence of iodine concentration on the photoelectrochemical performance of dye-sensitized solar cells containing non-volatile electrolyte [J].
Hao, Feng ;
Lin, Hong ;
Zhang, Jing ;
Zhuang, Dongtian ;
Liu, Yizhu ;
Li, Jianbao .
ELECTROCHIMICA ACTA, 2010, 55 (24) :7225-7229