Solid monolayers of fluorocarbons adsorbed on graphite from liquids

被引：8

作者：

Parker, J. E.

Clarke, S. M. ^{[1
]}

机构：

[1] Univ Cambridge, BP Inst, Cambridge CB3 0EZ, England

[2] Univ Cambridge, Dept Chem, Cambridge CB3 0EZ, England

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2007年 / 298卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

fluoroalkane; adsorbed layer; graphite; calorimetry; neutron diffraction;

D O I：

10.1016/j.colsurfa.2006.12.005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Calorimetry data from four perfluoroalkanes adsorbed on graphite is presented that indicates the formation of solid monolayers. This is supported by neutron diffraction measurements from an n-perfluorododecane monolayer on graphite. A monolayer crystal structure has been proposed for the perfluorododecane layer which is seen to be related to that of the C12 alkane, dodecane. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：145 / 147

页数：3

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