Electrophilic activation of hydrogen peroxide: Selective oxidation reactions in perfluorinated alcohol solvents

被引：150

作者：

Neimann, K ^{[1
]}

Neumann, R ^{[1
]}

机构：

[1] Weizmann Inst Sci, Dept Organ Chem, IL-76100 Rehovot, Israel

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 18期

关键词：

D O I：

10.1021/ol006287m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic electrophilic activation of hydrogen peroxide with transition metal compounds toward reaction with nucleophiles is a matter of very significant research and practical interest. We have now found that use of perfluorinated alcoholic solvents such as 1,1,1,3,3,3-hexafluoro-5-propanol in the absence of catalysts allowed electrophilic activation of hydrogen peroxide toward epoxidation of alkenes and the Baeyer-Villiger oxidation of ketones.

引用

页码：2861 / 2863

页数：3

共 50 条

[41] A novel and convenient process for the selective oxidation of naphthalenes with hydrogen peroxide [J].

Shi, Feng ;

Tse, Man Kin ;

Beller, Matthias .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (03) :303-308

[42] Selective Oxidation Using In Situ-Generated Hydrogen Peroxide [J].

Lewis, Richard J. ;

Hutchings, Graham J. .

ACCOUNTS OF CHEMICAL RESEARCH, 2023, 57 (01) :106-119

[43] Hydrogen peroxide in green oxidation reactions: Recent catalytic processes [J].

Goti, Andrea ;

Cardona, Francesca .

GREEN CHEMICAL REACTIONS, 2008, :191-212

[44] Advances in the Application of Urea-Hydrogen Peroxide to Oxidation Reactions [J].

Ji, Li ;

Liu, Jinqiang ;

Qian, Chao ;

Chen, Xinzhi .

CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (02) :254-265

[45] SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES/SULFONES BY 30% HYDROGEN PEROXIDE [J].

He, Ying ;

Ma, Xiaoyun ;

Ji, Hai Feng ;

Zha, Xin Bing ;

Jiang, Hongliang ;

Lu, Ming .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2012, 187 (07) :822-830

[46] Application of Hydrogen Peroxide Encapsulated in Silica Xerogels to Oxidation Reactions [J].

Bednarz, Szczepan ;

Rys, Barbara ;

Bogdal, Dariusz .

MOLECULES, 2012, 17 (07) :8068-8078

[47] Selective Electrochemical Generation of Hydrogen Peroxide from Water Oxidation [J].

Viswanathan, Venkatasubramanian ;

Hansen, Heine A. ;

Norskov, Jens K. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (21) :4224-4228

[48] Selective oxidation of monoterpenes with hydrogen peroxide catalyzed by peroxotungstophosphate (PCWP) [J].

Sakaguchi, S ;

Nishiyama, Y ;

Ishii, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (16) :5307-5311

[49] Selective oxidation of cyclohexane with hydrogen peroxide in the presence of copper pyrophosphate [J].

Du, Ying ;

Xiong, Yonglian ;

Li, Jing ;

Yang, Xiangguang .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 298 (1-2) :12-16

[50] Selective Oxidation of Monoterpenes with Hydrogen Peroxide Catalyzed by Peroxotungstophosphate (PCWP) [J].

J Org Chem, 16 (5307)

← 1 2 3 4 5 →