Spectroscopic investigation of modern pigments on purportedly medieval miniatures by the 'Spanish Forger'

被引:24
作者
Burgio, Lucia [1 ,3 ]
Clark, Robin J. H. [1 ]
Hark, Richard R. [2 ]
机构
[1] UCL, Christopher Ingold Labs, London WC1H 0AJ, England
[2] Juniata Coll, Dept Chem, Huntingdon, PA 16652 USA
[3] Victoria & Albert Museum, Sci Sect, Conservat Dept, London SW7 2RL, England
基金
英国工程与自然科学研究理事会;
关键词
pigments; Raman spectroscopy; X-ray fluorescence; forgeries; Spanish Forger; RESONANCE RAMAN-SPECTROSCOPY; IN-SITU; ULTRAMARINE BLUE; RADICAL-ANIONS; IDENTIFICATION; MICROSCOPY; GREEN; PAINTINGS; INDIGO; DYES;
D O I
10.1002/jrs.2364
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Five miniatures by the so-called 'Spanish Forger' were acquired by the Victoria and Albert Museum in 2008. Believed to be authentic medieval miniatures until the mid-twentieth century, they are now considered to have been painted around the end of the nineteenth and the beginning of the twentieth century. To investigate this attribution and to gather detailed knowledge about the materials used by the artist, a comprehensive pigment analysis by Raman microscopy and X-ray fluorescence was carried out. Although traditional materials such as vermilion, carbon black, red lead, lead white and indigo were identified, many others (chrome yellow, Scheele's green, emerald green and ultramarine blue) are modern and synthetic pigments, a result which provides a firm scientific basis for stating that the miniatures are forgeries. Copyright (C) 2009 John Wiley & Sons, Ltd.
引用
收藏
页码:2031 / 2036
页数:6
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