Synthesis of 1,2,4,5-tetrazines

被引:0
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作者
Singh, R [1 ]
Choubey, AK [1 ]
Shukla, AK [1 ]
Singh, PK [1 ]
机构
[1] Banaras Hindu Univ, Inst Technol, Dept Appl Chem, Varanasi 221005, Uttar Pradesh, India
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
1-[S-Benzylarylthiocarbamoyl]-2-(phenylcarbamyol) hydrazines, (Ila-e) have been obtained by the benzylation of 1-(arylthiocarbamoyl)-2-(phenylcarbamoyl) hydrazines (la-e), which in turn were obtained by condensation of arylisothiocyanates with 4-substituted phenylcarbamidohydrazine. The compounds, (la-e) and (la-e) on oxidative cyclization with molecular bromine resulted in the formation of corresponding 1-aryl-2-phenyl-3-oxo-6-thiono-1 ,2,4,5-tetrahydro-s-tetrazines (IVa-e) and 1-aryl-2-phenyl-3-oxo-6-benzylthio-1,2,4-trihydro-s-tetrazines (IIla-e) respectively.
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页码:173 / 176
页数:4
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