Group 5-7 transition metal oxides as efficient catalysts for oxidative functionalization of alkanes under mild conditions

被引：80

作者：

Kirillova, Marina V. ^{[1
]}

Kirillov, Alexander M. ^{[1
]}

Reis, Patricia M. ^{[1
]}

Silva, Jose A. L. ^{[1
]}

Frausto da Silva, Joao J. R. ^{[1
]}

Pombeiro, Armando J. L. ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

JOURNAL OF CATALYSIS | 2007年 / 248卷 / 01期

关键词：

Alkanes; C-H activation; carboxylation; peroxidative oxidation; carboxylic acids; homogeneous catalysis; metal oxides; vanadium; methyltrioxorhenium;

D O I：

10.1016/j.jcat.2007.02.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Oxides of group 5-7 metals are convenient and efficient catalysts for the single-pot carboxylation of gaseous (methane, ethane, propane) and liquid alkanes to carboxylic acids, as well as for the aqueous peroxidative hydroxylation/oxygenation of liquid alkanes to alcohols and ketones. The reactions occur under mild conditions, and the carboxylations proceed with unprecedented remarkably high turnover numbers. The diagonal metals commonly provide the most active oxide catalysts in the order V > Re > Mo. (C) 2007 Elsevier Inc. All rights reserved.

引用

页码：130 / 136

页数：7

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