Polyoxometalates: Building Blocks for Functional Nanoscale Systems

被引:2022
作者
Long, De-Liang [1 ]
Tsunashima, Ryo [1 ]
Cronin, Leroy [1 ]
机构
[1] Univ Glasgow, Dept Chem, WestCHEM, Glasgow G12 8QQ, Lanark, Scotland
基金
英国工程与自然科学研究理事会;
关键词
cluster compounds; metal oxides; self organization; nanoscience; polyoxometalates; CRYOSPRAY MASS-SPECTROMETRY; CELTIC-RING ISOPOLYOXOTUNGSTATE; KEGGIN-TYPE POLYOXOMETALATE; ELECTRON-TRANSFER REACTIONS; SINGLE-MOLECULE MAGNETS; HYDROGEN-PEROXIDE; AQUEOUS-SOLUTION; SOLID-STATE; CROWN-ETHER; SUBSTITUTED SILICOTUNGSTATE;
D O I
10.1002/anie.200902483
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyoxometalates (POMs) are a subset of metal oxides that represent a diverse range of molecular clusters with an almost unmatched range of physical properties and the ability to form dynamic structures that can range in size from the nano- to the micrometer scale. Herein we present the very latest developments from synthesis to structure and function of POMs. We discuss the possibilities of creating highly sophisticated functional hierarchical systems with multiple, interdependent, functionalities along with a critical analysis that allows the non-specialist to learn the salient features. We propose and present a periodic table ofpolyoxometalate building blocks". We also highlight some of the current issues and challenges that need to be addressed to work towards the design of functional systems based upon POM building blocks and look ahead to possible emerging application areas. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA."
引用
收藏
页码:1736 / 1758
页数:23
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