Stereoselective transition metal-catalyzed and radical polycyclizations

被引：0

作者：

Aubert, C ^{[1
]}

Courillon, C ^{[1
]}

Dhimane, AL ^{[1
]}

Fensterbank, L ^{[1
]}

Lacôte, E ^{[1
]}

Thorimbert, S ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Organ Synth, UMR 7611, F-75252 Paris 05, France

来源：

CURRENT OPINION IN DRUG DISCOVERY & DEVELOPMENT | 2002年 / 5卷 / 06期

关键词：

cycloaddition; cycloisomerization; metathesis; polycyclizadons; radical cascades; transition metal;

D O I：

暂无

中图分类号：

R9 [药学];

学科分类号：

1007 ;

摘要：

This short review presents a selection of metal-mediated and radical polycyclizations reported during the past two years. Palladium-catalyzed domino processes, cobalt-mediated cycloadditions and Pauson-Khand reactions catalyzed by rhodium are described. Ruthenium and platinum are shown as powerful metal catalysts in cyclizations, ring..closing metathesis and cycloisomerizations. Finally, recent examples of radical cascades, and their synthetic applications, are selected for their ability to build polycyclic compounds.

引用

页码：928 / 936

页数：9

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