The Halogen Bond

被引：3094

作者：

Cavallo, Gabriella ^{[1
]}

Metrangolo, Pierangelo ^{[1
,2
]}

Milani, Roberto ^{[2
]}

Pilati, Tullio ^{[1
]}

Priimagi, Arri ^{[3
]}

Resnati, Giuseppe ^{[1
]}

Terraneo, Giancarlo ^{[1
]}

机构：

[1] Politecn Milan, Dept Chem Mat & Chem Engn Giulio Natta, Lab Nanostruct Fluorinated Mat NFMLab, Via L Mancinelli 7, I-20131 Milan, Italy

[2] VTT Tech Res Ctr Finland, Biologinkuja 7, Espoo 02150, Finland

[3] Tampere Univ Technol, Dept Chem & Bioengn, Korkeakoulunkatu 8, FI-33101 Tampere, Finland

来源：

CHEMICAL REVIEWS | 2016年 / 116卷 / 04期

基金：

欧洲研究理事会; 芬兰科学院;

关键词：

CHARGE-TRANSFER COMPLEXES; CENTER-DOT-I; DONOR-ACCEPTOR COMPLEXES; PRE-REACTIVE COMPLEX; ROOM-TEMPERATURE PHOSPHORESCENCE; PROTEIN-KINASE CK2; GAS-PHASE COMPLEX; NUCLEAR-QUADRUPOLE RESONANCE; PERFLUORO-ORGANO BROMIDES; X-RAY-STRUCTURE;

D O I：

10.1021/acs.chemrev.5b00484

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity. In this fairly extensive review, after a brief history of the interaction, we will provide the reader with a snapshot of where the research on the halogen bond is now, and, perhaps, where it is going. The specific advantages brought up by a design based on the use of the halogen bond will be demonstrated in quite different fields spanning from material sciences to biomolecular recognition and drug design.

引用

页码：2478 / 2601

页数：124