Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

被引：93

作者：

Aoki, M ^{[1
]}

Kaneko, M ^{[1
]}

Izumi, S ^{[1
]}

Ukai, K ^{[1
]}

Iwasawa, N ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b411802b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni-0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.

引用

页码：2568 / 2569

页数：2

共 31 条

[11] C2-symmetric chiral bis(oxazoline)-metal complexes in catalytic asymmetric synthesis [J].

Ghosh, AK ;

Packiarajan, M ;

Cappiello, J .

TETRAHEDRON-ASYMMETRY, 1998, 9 (01) :1-45

[12] NICKEL(0) INDUCED C-C LINKAGE BETWEEN ALKENES AND CARBON-DIOXIDE [J].

HOBERG, H ;

SCHAEFER, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 236 (01) :C28-C30

[13] C-C COUPLING OF ALKENES WITH CO2 IN NICKEL(0) - PRODUCTION OF CINNAMIC ACID IN STYRENE [J].

HOBERG, H ;

PERES, Y ;

MILCHEREIT, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 307 (02) :C38-C40

[14] REACTION OF DIALKYL-SUBSTITUTED ALKYNES WITH CARBON-DIOXIDE CATALYZED BY NICKEL(0) COMPLEXES - INCORPORATION OF CARBON-DIOXIDE IN ALKYNE DIMERS AND NOVEL CYCLOTRIMERIZATION OF THE ALKYNES [J].

INOUE, Y ;

ITOH, Y ;

KAZAMA, H ;

HASHIMOTO, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (11) :3329-3333

[15] INCORPORATION OF CARBON-DIOXIDE IN ALKYNE OLIGOMERIZATION CATALYZED BY NICKEL(O) COMPLEXES - FORMATION OF SUBSTITUTED 2-PYRONES [J].

INOUE, Y ;

ITOH, Y ;

HASHIMOTO, H .

CHEMISTRY LETTERS, 1977, (08) :855-856

[16]

MEYER H, 1978, LIEBIGS ANN CHEM, P1491

[17]

MEYER H, 1981, LIEBIGS ANN CHEM, P1523

[18]

MEYER H, 1981, LIEBIGS ANN CHEM, P1545

[19]

Patai S., 1991, CHEM AMIDINES IMIDAT, V2

[20] Amidines Part II Diamidines from di-imidochlorides derived from diamines [J].

Rao, HKS ;

Wheeler, TS .

JOURNAL OF THE CHEMICAL SOCIETY, 1937, :1643-1645

← 1 2 3 4 →