Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

被引:93
作者
Aoki, M [1 ]
Kaneko, M [1 ]
Izumi, S [1 ]
Ukai, K [1 ]
Iwasawa, N [1 ]
机构
[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan
关键词
D O I
10.1039/b411802b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni-0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.
引用
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页码:2568 / 2569
页数:2
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