A novel electromagnetic biodegradable nanocomposite based on cellulose, polyaniline, and cobalt ferrite nanoparticles

被引:80
作者
Abou Hammad, A. B. [1 ]
Abd El-Azizb, M. E. [2 ]
Hasanin, M. S. [3 ]
Kamel, S. [3 ]
机构
[1] Natl Res Ctr, Solid State Dept, 33 El Bohouth St,PO 12622, Giza, Egypt
[2] Natl Res Ctr, Polymers & Pigments Dept, 33 El Bohouth St,PO 12622, Giza, Egypt
[3] Natl Res Ctr, Cellulose & Paper Dept, 33 El Bohouth St,PO 12622, Giza, Egypt
关键词
Cobalt ferrite nanoparticles; Polyaniline; Electrical properties; Cellulose; Magnetic properties; Antimicrobial; COFE2O4; NANOPARTICLES; MAGNETIC-PROPERTIES; ANTIBACTERIAL; NANOTUBES; FILMS;
D O I
10.1016/j.carbpol.2019.03.038
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Biodegradable, antimicrobial, and semiconducting cellulosic composite was synthesized by in-situ polymerization of polyaniline in the presence of cellulose. The cobalt ferrite nanoparticles (CFO-NPs) were added during the polymerization process to acquire this composite magnetic property. The CFO-NPs were prepared by sol-gel method with average particles size less than 50 nm. The nanocomposites were characterized by Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX). In addition, their magnetic, dielectric constant, dielectric loss, and conductivity behaviors were studied. The magnetization (M-s) and conductivity increased up to 3.7 emu/g and 3.5 x 10(-3) S/cm, respectively, with increasing CFO-NPs content. The prepared electromagnetic nanocomposite exhibits highly efficient biodegradability and antimicrobial activity against Escherichia coli, Bacillus subtilis, and Candida albicans. The antimicrobial activity increased with increasing CFO-NPs while the biodegradability decreased.
引用
收藏
页码:54 / 62
页数:9
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