The Cd isotope composition of atmospheric aerosols from the Tropical Atlantic Ocean

被引:39
作者
Bridgestock, Luke [1 ,2 ]
Rehkamper, Mark [1 ]
van de Flierdt, Tina [1 ]
Murphy, Katy [1 ]
Khondoker, Roulin [1 ]
Baker, Alex R. [3 ]
Chance, Rosie [3 ,4 ]
Strekopytov, Stanislav [5 ]
Humphreys-Williams, Emma [5 ]
Achterberg, Eric P. [6 ]
机构
[1] Imperial Coll London, Dept Earth Sci & Engn, London, England
[2] Univ Oxford, Dept Earth Sci, Oxford, England
[3] Univ East Anglia, Sch Environm Sci, Norwich, Norfolk, England
[4] Univ York, Dept Chem, Wolfson Atmospher Chem Lab, York, N Yorkshire, England
[5] Nat Hist Museum, Imaging & Anal Ctr, London, England
[6] Geomar Helmholtz Ctr Ocean Res, Kiel, Germany
关键词
cadmium isotopes; atmospheric aerosols; anthropogenic impacts; biogeochemical cycles; PRECISE DETERMINATION; WATER COLUMN; METAL POLLUTION; SOUTHERN-OCEAN; CADMIUM; FRACTIONATION; LEAD; PB; ZN; ZINC;
D O I
10.1002/2017GL072748
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Stable isotope compositions can potentially be used to trace atmospheric Cd inputs to the surface ocean and anthropogenic Cd emissions to the atmosphere. Both of these applications may provide valuable insights into the effects of anthropogenic activities on the cycling of Cd in the environment. However, a lack of constraints for the Cd isotope compositions of atmospheric aerosols is currently hindering such studies. Here we present stable Cd isotope data for aerosols collected over the Tropical Atlantic Ocean. The samples feature variable proportions of mineral dust-derived and anthropogenic Cd, yet exhibit similar isotope compositions, thus negating the distinction of these Cd sources by using isotopic signatures in this region. Isotopic variability between these two atmospheric Cd sources may be identified in other areas, and thus warrants further investigation. Regardless, these data provide important initial constraints on the isotope composition of atmospheric Cd inputs to the ocean.
引用
收藏
页码:2932 / 2940
页数:9
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