Iron-catalyzed selective reduction of nitro compounds to amines

被引：108

作者：

Pehlivan, Leyla ^{[1
]}

Metay, Estelle ^{[1
]}

Laval, Stephane ^{[1
]}

Dayoub, Wissam ^{[1
]}

Demonchaux, Patrice ^{[2
]}

Mignani, Gerard ^{[3
]}

Lemaire, Marc ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Lab Catalyse Synthese & Environm, ICBMS,UMR5246, F-69622 Villeurbanne, France

[2] Minakem SAS, F-59310 Beuvry La Foret, France

[3] Lyon Res Ctr, F-69192 St Fons, France

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 15期

关键词：

Reduction; Nitro; Amines; 1,1,3,3-Tetramethyldisiloxane; Iron catalyst; HYDROSILYLATION; COMPLEXES; AMINATION;

D O I：

10.1016/j.tetlet.2010.01.067

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient reduction of the nitro group with a catalytic amount of Fe(acac)(3) and TMDS in THF at 60 degrees C affording the corresponding amine is described. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1939 / 1941

页数：3

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