Directing self-assembly of nanoparticles at water/oil interfaces

被引:416
作者
Duan, HW [1 ]
Wang, DY [1 ]
Kurth, DG [1 ]
Möhwald, H [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
关键词
colloids; interfaces; nanoparticles; self-assembly; surface wettability;
D O I
10.1002/anie.200460920
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Finding the right angle: The contact angle of nanoparticles at the water/oil interface can be engineered close to 90° by capping with ligands containing carboxylic ester terminal groups. This drives the nanoparticles to self-assemble into close-packed films (see picture), and thus provides the opportunity to create two- or three-dimensional homo- or heterogeneous nanostructures for electronic, optoelectrical, and magnetic applications.
引用
收藏
页码:5639 / 5642
页数:4
相关论文
共 37 条
[1]   Emulsions stabilised solely by colloidal particles [J].
Aveyard, R ;
Binks, BP ;
Clint, JH .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2003, 100 :503-546
[2]   Particles as surfactants - similarities and differences [J].
Binks, BP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41
[3]   Reversible transference of Au nanoparticles across the water and toluene interface: A Langmuir type adsorption mechanism [J].
Chen, SH ;
Yao, H ;
Kimura, K .
LANGMUIR, 2001, 17 (03) :733-739
[4]   Nanocrystal superlattices [J].
Collier, CP ;
Vossmeyer, T ;
Heath, JR .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :371-404
[5]   Nanoparticles at air/water interfaces [J].
Fendler, JH .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1996, 1 (02) :202-207
[6]  
Hayat M.A., 1991, COLLOIDAL GOLD PRINC
[7]  
Kiely CJ, 2000, ADV MATER, V12, P640, DOI 10.1002/(SICI)1521-4095(200005)12:9<640::AID-ADMA640>3.0.CO
[8]  
2-J
[9]   Self-organization of large gold nanoparticle arrays [J].
Kim, B ;
Tripp, SL ;
Wei, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (32) :7955-7956
[10]   Nanoparticle assembly and transport at liquid-liquid interfaces [J].
Lin, Y ;
Skaff, H ;
Emrick, T ;
Dinsmore, AD ;
Russell, TP .
SCIENCE, 2003, 299 (5604) :226-229