The Effects of sodium and alkalinity on the microcrystalline structure and the steam gasification performance of Shengli lignite

被引:17
作者
Zhang, Xiaorong [1 ]
Wang, Jie [1 ]
Liu, Quansheng [1 ]
Te, Gusi [1 ]
Ban, Yanpeng [1 ]
Wang, Yan [1 ]
Li, Na [1 ]
He, Runxia [1 ]
Zhang, Yaosheng [1 ]
Zhi, Keduan [1 ]
机构
[1] Inner Mongolia Univ Technol, Coll Chem Engn, Inner Mongolia Key Lab High Value Funct Utilizat, Hohhot 010051, Inner Mongolia, Peoples R China
基金
中国国家自然科学基金;
关键词
Catalytic pyrolysis; Carbon microcrystalline structure; Char reactivity; Shengli lignite; CHAR STRUCTURE; COAL-CHAR; CARBONACEOUS MATERIALS; RAMAN-SPECTROSCOPY; PYROLYSIS; METAL; REACTIVITY; COMBUSTION; EARTH; XPS;
D O I
10.1016/j.jaap.2017.03.019
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The pyrolysis of Shengli lignite (SL-Raw) and sodium-based anion doped into coal samples (SL-NaOH, SL-Na2CO3 and SL-NaNO3) was analyzed by investigating the effects of sodium and alkalinity on the differences in crystallite structure of chars by XRD, Raman, XPS and FT-IR. The steam gasification of chars was performed in a fixed-bed reactor. The char gasification results showed that sodium and alkalinity have a catalytic effect on the char reactivity, and the chars have better activity when the sodium compounds are more alkaline. The XRD and Raman results showed that NaNO3, Na2CO3 and NaOH inhibited the growth of the aromatic ring structure, and the carbon microcrystalline structure of the chars was destroyed due to sodium atoms during pyrolysis. The XPS and FT-IR results indicated that the phenolic hydroxyl (C-OH) was converted into sodium phenolate (C-O-Na), and the reactivity of chars was better. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:227 / 233
页数:7
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