The coating performance of adipic acid modified and methacrylated bisphenol -: A based epoxy oligomers

被引:24
作者
Bayramoglu, Guelay [1 ]
Kahraman, M. Vezir [1 ]
Kayaman-Apohan, Nilhan [1 ]
Guengoer, Atilla [1 ]
机构
[1] MArmara Univ, Fac Art & Sci, Dept Chem, TR-34722 Kaclikoy Istanbul, Turkey
关键词
UV-curing; epoxyacrylate resins; hardness; stress; strain;
D O I
10.1002/pat.809
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the present work adipic acid modified and methacrylated bisphenol A based epoxy resins were prepared. The structures of oligomers were characterized by FT-IR. UV curable clear coatings were applied on aluminum substrates. The physical and mechanical properties of UV-cured coatings such as gel content, solvent resistance, hardness, gloss, flexibility and tensile tests were examined. In addition, the thermal behavior of coatings was also evaluated. It is observed that the tensile properties and thermal stabilities of modified epoxy methacrylate coatings mainly depend on the adipic acid content. The best results were obtained with 5 wt% adipic acid modification. Copyright (C) 2007 John Wiley & Sons, Ltd.
引用
收藏
页码:173 / 179
页数:7
相关论文
共 16 条
[1]  
AGARWAL D, 1983, J OIL COLOUR CHEM AS, V66, P123
[2]   Film performance and UV curing of epoxy acrylate resins [J].
Bajpai, M ;
Shukla, V ;
Kumar, A .
PROGRESS IN ORGANIC COATINGS, 2002, 44 (04) :271-278
[3]   Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings [J].
Chattopadhyay, DK ;
Panda, SS ;
Raju, KVSN .
PROGRESS IN ORGANIC COATINGS, 2005, 54 (01) :10-19
[4]   SYNTHESIS, STRUCTURE, AND THERMAL-PROPERTIES OF EPOXY-IMIDE RESIN CURED BY PHOSPHORYLATED DIAMINE [J].
CHIN, WK ;
SHAU, MD ;
TSAI, WC .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (03) :373-379
[5]   Preparation of novel UV-curable methacrylated urethane resins from a modified epoxy resin and isocyanatoethylmethacrylate (IEM) [J].
Inan, TY ;
Ekinci, E ;
Kuyulu, A ;
Güngör, A .
POLYMER BULLETIN, 2002, 47 (05) :437-444
[6]   The novel use of organo alkoxy silane for the synthesis of organic-inorganic hybrid coatings [J].
Kahraman, M. Vezir ;
Kugu, Murat ;
Menceloglu, Yusuf ;
Kayaman-Apohan, Nilhan ;
Gungor, Atilla .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (21-22) :2143-2151
[7]   Synthesis and characterization UV-curable organic-inorganic of flame retarding hybrid coatings [J].
Karatas, Sevim ;
Hosgor, Zuhal ;
Menceloglu, Yusuf ;
Kayaman-Apohan, Nilhan ;
Gungor, Atilla .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (02) :1906-1914
[8]   Synthesis and characterization of UV-curable vinyl ether functionalized urethane oligomers [J].
Kayaman-Apohan, N ;
Amanoel, A ;
Arsu, N ;
Güngör, A .
PROGRESS IN ORGANIC COATINGS, 2004, 49 (01) :23-32
[9]   Chalk resistant epoxy resins [J].
Malshe, VC ;
Waghoo, G .
PROGRESS IN ORGANIC COATINGS, 2004, 51 (03) :172-180
[10]  
Pappas S.P., 1978, UV curing: science and technology