The role of interfacial films in the mass transfer of naphthalene from creosotes to water

Viscous, semi-rigid interfacial films that are formed at the interface of certain multi-component non-aqueous phase liquid (NAPLs) and water can significantly reduce the rates of mass transfer of solutes. Creosote-water systems were investigated for their ability to form interfacial films. The effects of these films on the creosote-water partitioning and on mass transfer of a representative solute, naphthalene, were investigated in a series of experiments. The area-independent mass transfer coefficient of naphthalene contained in creosote decreased by 30% over a 1-week period in systems containing creosote and water. Further aging for up to 21 days did not result in significant additional decreases in the mass transfer coefficient. The creosote-water partition coefficient, however, did not change with extended contact. The presence of viscous interfacial films in creosote-water systems was demonstrated in pendant drop tests. These interfacial films most likely caused the reduction in solute mass transfer coefficients by providing significant resistance to the diffusion of solutes through the interfacial film. Results from mass transfer experiments conducted under different system conditions suggested that hindered diffusion of naphthalene through the bulk creosote phase, changes in composition of creosote as a result of extended dissolution, or changes in creosote-water interfacial area did not contribute to the decrease in naphthalene mass transfer coefficient. (C) 2004 Elsevier B.V. All rights reserved.