Facile synthesis of electrochemically active Pt nanoparticle decorated carbon nano onions

被引:12
作者
Lu, Haibo [1 ,2 ]
Eggers, Paul K. [2 ,3 ]
Gibson, Christopher T. [3 ]
Duan, Xiaofei [4 ]
Lamb, Robert N. [4 ]
Raston, Colin L. [3 ]
Chua, Hui Tong [1 ,5 ]
机构
[1] Univ Western Australia, Sch Mech & Chem Engn, Perth, WA 6009, Australia
[2] Univ Western Australia, Ctr Strateg Nanofabricat, Sch Biomed Biomol & Chem Sci, Nedlands, WA 6009, Australia
[3] Flinders Univ S Australia, Sch Chem & Phys Sci, Ctr NanoScale Sci & Technol, Bedford Pk, SA 5042, Australia
[4] Univ Melbourne, Surface Sci & Technol Grp, Sch Chem, Melbourne, Vic 3010, Australia
[5] Taiyuan Univ Technol, Sch Environm Sci & Engn, Taiyuan, Shanxi, Peoples R China
基金
澳大利亚研究理事会;
关键词
MEMBRANE FUEL-CELLS; PLATINUM NANOPARTICLES; HYDROGEN GAS; NANOTUBES; GRAPHENE; ELECTRODEPOSITION; ELECTROCATALYSTS; NANOMATERIALS; DEPOSITION; PALLADIUM;
D O I
10.1039/c4nj01378f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Well dispersed platinum nanoparticles 1-5 nm (average 2 nm) in diameter on carbon nano onions (CNOs) are accessible using a simple and scalable one-step batch method. This technique involves pretreatment of acid digested CNOs with H2PtCl6 prior to reduction using hydrogen at ambient conditions, with the composite material being electrochemically active. The effect of different Pt loading, surface treatment, and the processing temperature on the dispersion of platinum nanoparticles on the CNOs has been studied in detail.
引用
收藏
页码:915 / 920
页数:6
相关论文
共 30 条
  • [11] Progress in the synthesis of carbon nanotube- and nanofiber-supported Pt electrocatalysts for PEM fuel cell catalysis
    Lee, K
    Zhang, JJ
    Wang, HJ
    Wilkinson, DP
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2006, 36 (05) : 507 - 522
  • [12] Preparation and characterization of platinum-based electrocatalysts on multiwalled carbon nanotubes for proton exchange membrane fuel cells
    Liu, ZL
    Lin, XH
    Lee, JY
    Zhang, W
    Han, M
    Gan, LM
    [J]. LANGMUIR, 2002, 18 (10) : 4054 - 4060
  • [13] Pech D, 2010, NAT NANOTECHNOL, V5, P651, DOI [10.1038/NNANO.2010.162, 10.1038/nnano.2010.162]
  • [14] Carbon nano-onions for supercapacitor electrodes: recent developments and applications
    Plonska-Brzezinska, Marta E.
    Echegoyen, Luis
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (44) : 13703 - 13714
  • [15] Electrochemical Properties of Oxidized Carbon Nano-Onions: DRIFTS-FTIR and Raman Spectroscopic Analyses
    Plonska-Brzezinska, Marta E.
    Dubis, Alina T.
    Lapinski, Andrzej
    Villalta-Cerdas, Adrian
    Echegoyen, Luis
    [J]. CHEMPHYSCHEM, 2011, 12 (14) : 2659 - 2668
  • [16] Controllable Deposition of Platinum Nanoparticles on Graphene As an Electrocatalyst for Direct Methanol Fuel Cells
    Qiu, Jian-Ding
    Wang, Guo-Chong
    Liang, Ru-Ping
    Xia, Xing-Hua
    Yu, Hong-Wen
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (31) : 15639 - 15645
  • [17] Characterisation of carbon nano-onions using Raman spectroscopy
    Roy, D
    Chhowalla, M
    Wang, H
    Sano, N
    Alexandrou, I
    Clyne, TW
    Amaratunga, GAJ
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 373 (1-2) : 52 - 56
  • [18] The decoration of carbon nanotubes by metal nanoparticles
    Satishkumar, BC
    Vogl, EM
    Govindaraj, A
    Rao, CNR
    [J]. JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1996, 29 (12) : 3173 - 3176
  • [19] Electrocatalytically Active Graphene-Platinum Nanocomposites. Role of 2-D Carbon Support in PEM Fuel Cells
    Seger, Brian
    Kamat, Prashant V.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (19) : 7990 - 7995
  • [20] Exfoliated Graphene Separated by Platinum Nanoparticles
    Si, Yongchao
    Samulski, Edward T.
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (21) : 6792 - 6797