Three-Dimensional Layer-by-Layer Anode Structure Based on Co3O4 Nanoplates Strongly Tied by Capillary-like Multiwall Carbon Nanotubes for Use in High-Performance Lithium-Ion Batteries

被引:30
|
作者
Lee, Tae Il [1 ]
Jegal, Jong-Pil [2 ]
Park, Ji-Hyeon [2 ]
Choi, Won Jin [3 ]
Lee, Jeong-O [3 ]
Kim, Kwang-Bum [2 ]
Myoung, Jae-Min [2 ]
机构
[1] Gachon Univ, Coll BioNano Technol, Gyeonggi 461701, South Korea
[2] Yonsei Univ, Dept Mat Sci & Engn, Seoul 120749, South Korea
[3] Korea Res Inst Chem Technol KRICT, Adv Mat Div, Taejon 305343, South Korea
基金
新加坡国家研究基金会;
关键词
layer by layer; Li ion battery; carbon nanotube; cobalt oxide; nanoplate; ELECTRODE MATERIALS; COBALT OXIDES; HIGH-CAPACITY; BINDER-FREE; STORAGE; HYBRID;
D O I
10.1021/am5083599
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A layer-by-layer (LBL) structure composed of Co3O4 nanoplates and capillary-like three-dimensional (3D) multiwall carbon nanotube (MWCNT) nets was developed as an anode with simultaneous high-rate and long-term cycling performance, in a lithium-ion battery. As the current density was increased to 50 A g(-1), the LBL structure exhibited excellent long-term cycling and rate performance. Thug, the Co3O4 nanoplates were in good electrical contact with the capillary-like 3D MWCNT net under Mechanically severe strain during long-term, high-rate cyclic operation.
引用
收藏
页码:3861 / 3865
页数:5
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