Soluble Dicyanodistyrylbenzene-Based Non-Fullerene Electron Acceptors with Optimized Aggregation Behavior for High-Efficiency Organic Solar Cells

被引:76
作者
Kwon, Oh Kyu [1 ]
Park, Jung-Hwa [1 ]
Park, Sang Kyu [1 ]
Park, Soo Young [1 ]
机构
[1] Seoul Natl Univ, Dept Mat Sci & Engn, Ctr Supramol Optoelect Mat, Seoul 151744, South Korea
基金
新加坡国家研究基金会;
关键词
POWER CONVERSION EFFICIENCY; HIGH-PERFORMANCE; NAPHTHALENE DIIMIDES; CONJUGATED POLYMERS; SMALL MOLECULES; DONOR; TRANSPORT; DESIGN; HETEROJUNCTIONS; FLUORESCENT;
D O I
10.1002/aenm.201400929
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new class of small molecules based on dicyanodistyrylbenzene combined with naphthalimide is developed for use as non-fullerene electron acceptors in bulk heterojunction organic solar cells. The optical, electrochemical, and film formation characteristics of the new materials are found to be suitable for preparing solution-processed devices. Solar cells prepared with poly(3-hexylthiophene) (P3HT) as a donor material exhibit a maximum power conversion efficiency of 2.71%.
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页数:6
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  • [1] Design of New Electron Acceptor Materials for Organic Photovoltaics: Synthesis, Electron Transport, Photophysics, and Photovoltaic Properties of Oligothiophene-Functionalized Naphthalene Diimides
    Ahmed, Eilaf
    Ren, Guoqiang
    Kim, Felix S.
    Hollenbeck, Emily C.
    Jenekhe, Samson A.
    [J]. CHEMISTRY OF MATERIALS, 2011, 23 (20) : 4563 - 4577
  • [2] π-Conjugated Cyanostilbene Derivatives: A Unique Self-Assembly Motif for Molecular Nanostructures with Enhanced Emission and Transport
    An, Byeong-Kwan
    Gierschner, Johannes
    Park, Soo Young
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (04) : 544 - 554
  • [3] Comparing the Device Physics and Morphology of Polymer Solar Cells Employing Fullerenes and Non-Fullerene Acceptors
    Bloking, Jason T.
    Giovenzana, Tommaso
    Higgs, Andrew T.
    Ponec, Andrew J.
    Hoke, Eric T.
    Vandewal, Koen
    Ko, Sangwon
    Bao, Zhenan
    Sellinger, Alan
    McGehee, Michael D.
    [J]. ADVANCED ENERGY MATERIALS, 2014, 4 (12)
  • [4] Solution-Processed Organic Solar Cells with Power Conversion Efficiencies of 2.5% using Benzothiadiazole/Imide-Based Acceptors
    Bloking, Jason T.
    Han, Xu
    Higgs, Andrew T.
    Kastrop, John P.
    Pandey, Laxman
    Norton, Joseph E.
    Risko, Chad
    Chen, Cynthia E.
    Bredas, Jean-Luc
    McGehee, Michael D.
    Sellinger, Alan
    [J]. CHEMISTRY OF MATERIALS, 2011, 23 (24) : 5484 - 5490
  • [5] Binary additives synergistically boost the efficiency of all-polymer solar cells up to 3.45%
    Cheng, Pei
    Ye, Long
    Zhao, Xingang
    Hou, Jianhui
    Li, Yongfang
    Zhan, Xiaowei
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (04) : 1351 - 1356
  • [6] Rational design on n-type organic materials for high performance organic photovoltaics
    Chochos, Christos L.
    Tagmatarchis, Nikos
    Gregoriou, Vasilis G.
    [J]. RSC ADVANCES, 2013, 3 (20): : 7160 - 7181
  • [7] Dual-Mode Switching in Highly Fluorescent Organogels: Binary Logic Gates with Optical/Thermal Inputs
    Chung, Jong Won
    Yoon, Seong-Jun
    Lim, Seon-Jeong
    An, Byeong-Kwan
    Park, Soo Young
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (38) : 7030 - 7034
  • [8] Transient photoconductivity in polymer bulk heterojunction solar cells: Competition between sweep-out and recombination
    Cowan, Sarah R.
    Street, R. A.
    Cho, Shinuk
    Heeger, A. J.
    [J]. PHYSICAL REVIEW B, 2011, 83 (03):
  • [9] 25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research
    Dou, Letian
    You, Jingbi
    Hong, Ziruo
    Xu, Zheng
    Li, Gang
    Street, Robert A.
    Yang, Yang
    [J]. ADVANCED MATERIALS, 2013, 25 (46) : 6642 - 6671
  • [10] All-Polymer Solar Cells with 3.3% Efficiency Based on Naphthalene Diimide-Selenophene Copolymer Acceptor
    Earmme, Taeshik
    Hwang, Ye-Jin
    Murari, Nishit M.
    Subramaniyan, Selvam
    Jenekhe, Samson A.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (40) : 14960 - 14963