Regioselecitive Huisgen Cycloaddition within Porous Coordination Networks

被引：39
|
作者：
Kawamichi, Takehide [1 ]
Inokuma, Yasuhide [1 ]
Kawano, Masaki [2 ]
Fujita, Makoto [1 ]
机构：
[1] Univ Tokyo, Dept Appl Chem, Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan
[2] POSTECH, Dept Chem, Pohang 790784, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 13期
基金：
日本科学技术振兴机构;
关键词：
azides; cycloaddition; solid-state structures; huisgen reactions; METAL-ORGANIC FRAMEWORK; CATALYSIS; POLYMERS; CRYSTAL; CHEMISTRY; BINDING; DESIGN; PORES;
D O I：
10.1002/anie.201000018
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Pore it on: Huisgen 1,3-dipolarcycloaddition reactions of 2-(azidomethyl)triphenylene and alkynes (see scheme) took place within the pores of a porous coordination network in a single-crystal-tosingle-crystal fashion. Columnar π stacks and nanosized pores in the network complex enforce a particular orientation of the reactants such that the 1,4-substituted isomer of the 1,2,3-triazole product is selectively produced. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2375 / 2377
页数：3
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