Resonant inelastic x-ray scattering of curium oxide

被引:15
|
作者
Kvashnina, K. O.
Butorin, S. M.
Shuh, D. K.
Guo, J. -H.
Werme, L.
Nordgren, J.
机构
[1] Uppsala Univ, Dept Phys, SE-75121 Uppsala, Sweden
[2] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA
[3] Lawrence Berkeley Natl Lab, Adv Light Source, Berkeley, CA 94720 USA
[4] SKB, Stockholm, Sweden
关键词
D O I
10.1103/PhysRevB.75.115107
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The measurements on radioactive actinide isotopes (curium-248) were performed using very small sample quantities (micrograms) to minimize the sample activity. Resonant inelastic x-ray scattering (RIXS) spectra of curium oxide at the Cm 5d edge were measured for the first time. RIXS data are compared with theoretical calculations using atomic multiplet theory. The results indicate that isotope curium -248 in the curium oxide sample has oxidation state III due to the best agreement with RIXS calculations for Cm (III) instead of those for Cm (IV).
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页数:7
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