Synthesis of flexible polymeric shielding materials for soft gamma rays: Physicomechanical and attenuation characteristics of radiation crosslinked polydimethylsiloxane/Bi2O3 composites

被引：38

作者：

Dubey, K. A. ^{[1
]}

Chaudhari, C. V. ^{[1
]}

Suman, S. K. ^{[2
]}

Raje, N. ^{[3
]}

Mondal, R. K. ^{[1
]}

Grover, V. ^{[4
]}

Murali, S. ^{[2
]}

Bhardwaj, Y. K. ^{[1
]}

Varshney, L. ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Radiat Technol Dev Div, Bombay 400085, Maharashtra, India

[2] Bhabha Atom Res Ctr, Radiat Safety Syst Div, Bombay 400085, Maharashtra, India

[3] Bhabha Atom Res Ctr, Div Analyt Chem, Bombay 400085, Maharashtra, India

[4] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India

来源：

POLYMER COMPOSITES | 2016年 / 37卷 / 03期

关键词：

EFFECTIVE ATOMIC NUMBERS; SILICONE-RUBBER; STABILITY; LINKING; ETHER; MWNT;

D O I：

10.1002/pc.23232

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Flexible lead-free high energy radiation shielding material was developed through internal compounding. Polymer-filler interaction, crosslinking density, specific gravity, physicomechanical characteristics, percentage attenuation, and thermal stability of the crosslinked composites were estimated. It was found that even at very high filler loading composites can be crosslinked; however, the crosslinking density was composition dependent and was highest in 10-50 wt% loading range at 100 kGy and 200 kGy. The Nielsen model was applied to understand the micromechanics of the system. Attenuation of gamma radiation from Am241 was not affected by the crosslinking density. Thermal stability of the composites was found to be significantly affected with bismuth oxide loading. POLYM. COMPOS., 37:756-762, 2016. (c) 2014 Society of Plastics Engineers

引用

页码：756 / 762

页数：7

共 28 条

[1] A REVIEW OF PARTICULATE REINFORCEMENT THEORIES FOR POLYMER COMPOSITES [J].

AHMED, S ;

JONES, FR .

JOURNAL OF MATERIALS SCIENCE, 1990, 25 (12) :4933-4942

[2] Feasibility study of gamma-ray medical radiography [J].

Alyassin, Abdalmajeid M. ;

Maqsoud, Hamza A. ;

Mashat, Ahmad M. ;

Al-Mohr, Al-Sayed ;

Abdulwajid, Subhan .

APPLIED RADIATION AND ISOTOPES, 2013, 72 :16-29

[3] Radiation effects on styrene-butadiene-ethylene-propylene diene monomer-multiple walled carbon nanotube nanocomposites: vulcanization and characterization [J].

Dubey, K. A. ;

Bhardwaj, Y. K. ;

Chaudhari, C. V. ;

Goel, N. K. ;

Sabharwal, S. ;

Rajkumar, K. ;

Chakraborty, S. K. .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (12) :1888-1897

[4] Radiation processed ethylene vinyl acetate-multiple walled carbon nanotube nano-composites: Effect of MWNT addition on the gel content and crosslinking density [J].

Dubey, K. A. ;

Bhardwaj, Y. K. ;

Chaudhari, C. V. ;

Kumar, Virendra ;

Goel, N. K. ;

Sabharwal, S. .

EXPRESS POLYMER LETTERS, 2009, 3 (08) :492-500

[5] Electron beam processing of LDPE/EVA/PCR ternary blends: radiation sensitivity evaluation and physico-mechanical characterization [J].

Dubey, Kumar A. ;

Bhardwaj, Yatender K. ;

Chaudhari, Chandrashekhar V. ;

Sarma, Kuppa S. S. ;

Goel, Narender K. ;

Sabharwal, Sunil .

JOURNAL OF POLYMER RESEARCH, 2011, 18 (01) :95-103

[6] LDPE/EVA/PCR/MWNT Nanocomposites: Radiation Crosslinking and Physicomechanical Characteristics [J].

Dubey, Kumar Abhinav ;

Bhardwaj, Yatender K. ;

Chaudhari, Chandrashekhar V. ;

Sabharwal, Sunil .

POLYMER COMPOSITES, 2011, 32 (05) :737-746

[7] Comparison of bismuth trioxide and antimony trioxide as synergists with decabromodiphenyl ether in flame retardancy of high-impact polystyrene [J].

Felix, Tais ;

Pinto, Orlando P., Jr. ;

Peres, Augusto ;

Costa, Joao M. ;

Sayer, Claudia ;

Morgan, Alexander B. ;

Araujo, Pedro H. H. .

JOURNAL OF FIRE SCIENCES, 2012, 30 (06) :566-574

[8]

Flory P.J., 1953, PRINCIPLES POLYM CHE, V495

[9] Statistical mechanics of cross-linked polymer networks II Swelling [J].

Flory, PJ ;

Rehner, J .

JOURNAL OF CHEMICAL PHYSICS, 1943, 11 (11) :521-526

[10] Productive inefficiency analysis and toxic chemical substances in US and Japanese manufacturing sectors [J].

Fujii, Hidemichi ;

Managi, Shunsuke .

ASIAN BUSINESS & MANAGEMENT, 2012, 11 (03) :291-310

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