Studies on the Role of Nitrogen in the Feed for Fischer-Tropsch Synthesis Under Fixed-Bed Reactor System

被引：6

作者：

Hong, Gi Hoon ^{[1
,2
]}

Jung, Jae-Sun ^{[1
,2
]}

Kim, Na-Young ^{[1
,3
]}

Lee, Sang Yong ^{[1
,3
]}

Moon, Dong Ju ^{[1
,2
]}

机构：

[1] KIST, Clean Energy Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea

[2] UST, Clean Energy Chem Engn, 217 Gajeong Ro, Dae Jeon 34113, South Korea

[3] Korea Univ, Chem & Biol Engn, 145 Anam Ro, Seoul 02841, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2016年 / 16卷 / 02期

关键词：

Fischer-Tropsch Synthesis; Nitrogen; GTL-FPSO; CATALYST; COBALT;

D O I：

10.1166/jnn.2016.11938

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, Co/Al2O3 catalyst for Fischer-Tropsch synthesis was prepared via slurry impregnation method and the catalyst was characterized by various techniques such as TPR, XRD, TGA and N-2 physisorption. To dissolve the wax, after-reaction catalyst was dewaxed using n-Hexane at 60 degrees C. The experiments were performed in a bench-scale fixed -bed reactor, under the reaction condition of 230 degrees C, 20 bar and feed volume ratio of H-2:CO:N-2 = 2:1:0.5-1.5. The methane selectivity and the ratio of olefin to paraffin among C-2-C-4 hydrocarbons were increased with higher contents of nitrogen in feed gas which result in higher partial pressure ratio of H-2 to CO, and also affect methane selectivity which has a significant role in increased CO conversion.

引用

页码：1894 / 1897

页数：4

共 12 条

[1]

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[2]

Choi G. N., 1997, 14 PITTSB COAL C PIT

[3]

Collier P. J., 2000, 219 NAT M AM CHEM SO, P199

[4] Nitrogen-Rich Natural Gases as a Potential Direct Feedstock for Some Novel Methane Transformation Processes. Part 1: Oxidative Processes [J].