Insertion of arynes into carbon-halogen σ-bonds:: regioselective acylation of aromatic rings

被引：51

作者：

Yoshida, Hiroto ^{[1
]}

Mimura, Yasuhiro ^{[1
]}

Ohshita, Joji ^{[1
]}

Kunai, Atsutaka ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 23期

关键词：

FRIEDEL-CRAFTS ACYLATION; PALLADIUM COMPLEX; DISTANNYLATION; DERIVATIVES; TRIFLATE;

D O I：

10.1039/b701581j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arynes were found to insert into carbon-halogen s-bonds of various acid halides, enabling acyl and halogen moieties to be introduced simultaneously into adjacent positions of aromatic rings.

引用

页码：2405 / 2407

页数：3

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