Synthesis and characterization of lanthanide complexes involving cyclopentadienyl and benzohydroximic acid ligand

被引：0

作者：

Wang, XR ^{[1
]}

Wan, YB ^{[1
]}

Hu, JP ^{[1
]}

机构：

[1] Anhui Normal Univ, Inst Organ Chem, Wuhu 241000, Peoples R China

来源：

JOURNAL OF RARE EARTHS | 2000年 / 18卷 / 04期

关键词：

rare earths; benzohydroximic acid; lanthanide complexes; synthesis;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

By the reaction of Cp(3)Ln with HL(Cp = eta (5)-C5H5 cyclopentadienyl; Ln = Yb, Tm, Er, Ho, Dy, Gd, Pr; HL = benzohydroximic acid), seven new complexes of the general formula Cp(2)LnL were synthesized. All the complexes were characterized by elemental analysis, infrared spectra, and mass spectra. Based on these data, the probable structure was proposed.

引用

页码：315 / 317

页数：3

共 6 条

[1]

BATT AH, 1944, BENZOHYDROXIMIC ACID, V2, P67

[2] ORGANOLANTHANIDES AND ORGANOACTINIDES .15. SYNTHESIS AND PROPERTIES OF NEW SIGMA-BONDED ORGANOLANTHANIDE COMPLEXES [J].

ELY, NM ;

TSUTSUI, M .

INORGANIC CHEMISTRY, 1975, 14 (11) :2680-2687

[3]

LIU G, 1989, HUA XUE TONG BAO, V1, P42

[4]

LIU Y, 1981, YOU JI HUA XUE, V3, P210

[5] STUDIES ON ORGANOLANTHANIDE COMPLEXES .3. THE STABILIZATION OF EARLY LANTHANOCENE CHLORIDES BY USING A RING-BRIDGED DICYCLOPENTADIENE LIGAND [J].

QIAN, CT ;

YE, CQ ;

LU, HZ ;

LI, YQ ;

HUANG, YZ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 263 (03) :333-343

[6] CYCLOPENTADIENYL COMPOUNDS OF SC, Y, LA, CE AND SOME LANTHANIDE ELEMENTS [J].

WILKINSON, G ;

BIRMINHAM, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (23) :6210-6210

← 1 →