Apotirucallane and tirucallane triterpenoids from Luvunga sarmentosa

被引:25
作者
Kamperdick, C
Lien, TP
Adam, G
Van Sung, T
机构
[1] Natl Ctr Nat Sci & Technol Vietnam, Inst Chem, Hanoi, Vietnam
[2] Inst Plant Biochem, D-06120 Halle Saale, Germany
来源
JOURNAL OF NATURAL PRODUCTS | 2003年 / 66卷 / 05期
关键词
D O I
10.1021/np020458+
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
The leaves of Luvunga sarmentosa yielded two new apotirucallane triterpenoids, 3-epi-skimmiarepin A (1) and 21,23-epoxy-7alpha,21-dihydroxyapotirucalla-14,24-dien-3-one (2), and a new tirucallane triterpene, 3-epi-flindissol (3). Because of a hemiacetal functionality at C-21, all compounds occurred as mixtures of 21-epimers. 3-epi-Skimmiarepin A (1) and 3-epi-flindissol (3) were oxidized to the corresponding gamma-lactones. The structures have been elucidated on the basis of mass and NMR spectroscopic methods.
引用
收藏
页码:675 / 678
页数:4
相关论文
共 8 条
  • [1] GUANGYI L, 1988, PHYTOCHEMISTRY, V27, P2283
  • [2] HO PH, 1993, CAY CO VIETNAM ILLUS, V2, P534
  • [3] ITOKAWA H, 1992, CHEM PHARM BULL, V40, P1053, DOI 10.1248/cpb.40.1053
  • [4] LAVIE D, 1969, Tetrahedron Letters, V40, P3525
  • [5] Apotirucallane triterpenoids from Luvunga sarmentosa (Rutaceae)
    Lien, TP
    Kamperdick, C
    Schmidt, J
    Adam, G
    Sung, TV
    [J]. PHYTOCHEMISTRY, 2002, 60 (07) : 747 - 754
  • [6] SKIMMIAREPIN A AND B, 2 NEW INSECT GROWTH INHIBITORY TRITERPENOIDS FROM SKIMMIA-JAPONICA THUNB VAR INTERMEDIA KOMATSU F-REPENS (NAKAI) HARA
    OCHI, M
    TATSUKAWA, A
    SEKI, N
    KOTSUKI, H
    SHIBATA, K
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (09) : 3225 - 3229
  • [7] PERRY LM, 1980, MED PLANTS E SE ASIA, P371
  • [8] CHEMICAL-CONSTITUENTS OF 3 RUTACEAE SPECIES FROM SRI-LANKA
    WIJERATNE, EMK
    BANDARA, BMR
    GUNATILAKA, AAL
    TEZUKA, Y
    KIKUCHI, T
    [J]. JOURNAL OF NATURAL PRODUCTS, 1992, 55 (09): : 1261 - 1269