Enhancement in some physical properties of spray deposited CdO:Mn thin films through Zn doping towards optoelectronic applications

被引:37
作者
Manjula, N. [1 ]
Balu, A. R. [1 ]
Usharani, K. [1 ]
Raja, N. [1 ]
Nagarethinam, V. S. [1 ]
机构
[1] AVVM Sri Pushpam Coll, PG & Res Dept Phys, Poondi 613503, Tamil Nadu, India
来源
OPTIK | 2016年 / 127卷 / 16期
关键词
Grain boundaries; Crystal structure; Red shift; Blue shift; Carrier concentration; TEMPERATURE; MECHANISM;
D O I
10.1016/j.ijleo.2016.04.129
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
This paper reports the enhancement in the structural, morphological and opto-electrical properties of spray deposited CdO:Mn thin films through Zn doping. Mn concentration is maintained as 1 at.% for all the films whereas Zn concentration in CdO:Mn film is varied as 1, 2 and 3 wt.%. XRD studies showed that the crystalline quality of pure CdO deteriorates with Mn doping which got enhanced with Zn doping. The entire doped films exhibit a (1 1 1) preferential orientation similar to that of the undoped film. Cauliflower shaped nanostructures are evinced for all the films from the FESEM images. The decreased transparency of pure CdO with Mn doping increases with Zn doping and a maximum transmittance of 89.8% is obtained for the CdO:Mn film coated with 2 wt.% Zn concentration. Optical band gap of pure CdO which exhibits a red shift with Mn doping got blue shifted with Zn doping. Electrical studies showed that the CdO:Mn film is more resistive than the undoped film which experience a decrement with Zn doping. The obtained results confirm that CdO:Mn film when doped with zinc finds application in optoelectronic devices due to their enhanced opto-electrical properties. (C) 2016 Elsevier GmbH. All rights reserved.
引用
收藏
页码:6400 / 6406
页数:7
相关论文
共 24 条
[1]   Electrospinning preparation and characterization of cadmium oxide nanofibers [J].
Bazargan, A. M. ;
Fateminia, S. M. A. ;
Ganji, M. Esmaeilpour ;
Bahrevar, M. A. .
CHEMICAL ENGINEERING JOURNAL, 2009, 155 (1-2) :523-527
[2]  
Chopra KL., 1993, Thin Film Solar Cells
[3]   Preparation of nanostructured Bi-doped CdO thin films by sol-gel spin coating method [J].
Dagdelen, F. ;
Serbetci, Z. ;
Gupta, R. K. ;
Yakuphanoglu, F. .
MATERIALS LETTERS, 2012, 80 :127-130
[4]   Investigation on the catalytic activity of doped low-percentage oxide catalysts Mn/ZnO obtained from oxalate precursor [J].
Donkova, Borjana V. ;
Milenova, Katja I. ;
Mehandjiev, Dimitar R. .
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2008, 6 (01) :115-124
[5]  
Dutta S., 2007, J PHYS CONDENS MATT, V19
[6]   Chemical composition and electrical conduction mechanism for CdO:F thin films deposited by spray pyrolysis [J].
Ferro, R ;
Rodríguez, JA ;
Vigil, O ;
Morales-Acevedo, A .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2001, 87 (01) :83-86
[7]   Effect of indium doping in CdO thin films prepared by spray pyrolysis technique [J].
Kumaravel, R. ;
Ramamurthi, K. ;
Krishnakumar, V. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2010, 71 (11) :1545-1549
[8]   Effect of doping concentration on the structural, morphological, optical and electrical properties of Mn-doped CdO thin films [J].
Manjula, N. ;
Pugalenthi, M. ;
Nagarethinam, V. S. ;
Usharani, K. ;
Balu, A. R. .
MATERIALS SCIENCE-POLAND, 2015, 33 (04) :774-781
[9]   Doping concentration and annealing temperature effects on the properties of nanostructured ternary CdZnO thin films towards optoelectronic applications [J].
Noorunisha, T. ;
Nagarethinam, V. S. ;
Suganya, M. ;
Praba, D. ;
Ilangovan, S. ;
Usharani, K. ;
Balu, A. R. .
OPTIK, 2016, 127 (05) :2822-2829
[10]   Properties of Cd doped PbS thin films: doping concentration effect [J].
Rajashree, C. ;
Balu, A. R. ;
Nagarethinam, V. S. .
SURFACE ENGINEERING, 2015, 31 (04) :316-321