MnII-based MIL-53 Analogues: Synthesis Using Neutral Bridging μ2-Ligands and Application in Liquid-Phase Adsorption and Separation of C6-C8 Aromatics

被引：107
作者：
Xu, Guohai [1 ]
Zhang, Xiaoguang [1 ]
Guo, Peng [1 ]
Pan, Chengling [1 ]
Zhang, Hongjie [1 ]
Wang, Cheng [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 11期
关键词：
METAL-ORGANIC FRAMEWORKS; SELECTIVE ADSORPTION; XYLENE ISOMERS; BENZENE; BENZENEDICARBOXYLATE; ETHYLBENZENE; SORPTION; REDOX; DIMER; BTEX;
D O I：
10.1021/ja910818a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four Mn-II-based MIL-53 single crystals were prepared using Four neutral pyridine N-oxides as bridging Q-ligands. In the case of 4,4'-bipridine-N,N'-dioxide (BPNO), the infinite manganese oxide chains were Further interconnected by BPNO besides BDC, which allows I D channels to be accessible for guest molecules. The liquid-phase adsorption and separation of C6-C8 aromatics using the evacuated compound as an absorbent were investigated via crystal-to-crystal trails formations. Both structural evolution of the compounds and selectivity of C6-C7 aromatics of one evacuated compound Could be attributed to noncovalent interactions, especially pi-pi interaction.
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页码：3656 / +
页数：4
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