Solubility investigations in the systems K2B4O7+Li2B4O7+H2O and Na2B4O7+Li2B4O7+H2O at T=288 K

被引：22
|
作者：
Sang, SH [1 ]
Yin, HA [1 ]
Tang, ML [1 ]
Lei, NF [1 ]
机构：
[1] Chengdu Univ Technol, Dept Appl Chem, Chengdu 610059, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2004年 / 49卷 / 06期
关键词：
D O I：
10.1021/je034280k
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of the salt and the density, electrical conductivity, and pH of ternary systems K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T = 288 K were determined. On the basis of the experimental results, phase diagrams and property composition diagrams were derived. Phase equilibrium solids were Na(2)B(4)O(7)(.)10H(2)O, K(2)B(4)O(7)(.)4H(2)O, and Li(2)B(4)O(7)(.)3H(2)O. Analyses of what was made on the crystallization areas in the phase diagram were discussed. The results of properties in the solution were also discussed simply.
引用
收藏
页码：1586 / 1589
页数：4
相关论文
共 50 条
  • [41] The phase and density diagrams of the systems MgCl2-MgB4O7-H2O and KCl-K2B4O7-H2O at 273 K
    Zhao, Xiang-Po
    Zhang, Xue-Ping
    Sang, Shi-Hua
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (10) : 1932 - 1938
  • [42] (Liquid plus solid) phase equilibria in the quaternary system Na2CO3+K2B4O7+K2CO3+Na2B4O7+H2O at 288 K
    Sang, SH
    Yin, HA
    Tang, ML
    Zeng, Y
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (06): : 1775 - 1777
  • [43] Phase Equilibria in the Quaternary Systems KCI-K2B4O7-K2SO4-H2O and MgCl2-MgB4O7-MgSO4-H2O at 273 K
    Zhao, Xiang-Po
    Zhang, Xue-Ping
    Yang, Yu-Yan
    Sang, Shi-Hua
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (04): : 1377 - 1383
  • [44] Solid-Liquid Phase Equilibria of the Quaternary system Li2SO4-LiBO2-Li2B4O7-H2O and the Ternary Subsystem LiBO2-Li2B4O7-H2O at T=288.15 K and p=0.1 MPa
    Yang, Xiuxiu
    Chen, Lele
    Guo, Yafei
    Li, Dan
    Deng, Tianlong
    Meng, Lingzong
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (09): : 3463 - 3472
  • [45] Formation of silver nanoparticles in Li2B4O7-Ag2O and Li2B4O7-Gd2O3-Ag2O borate glasses
    Adamiv, Volodymyr
    Gamernyk, Roman
    Teslyuk, Ihor
    APPLIED OPTICS, 2017, 56 (17) : 5068 - 5072
  • [46] RASTVORIMOST V SISTEME (2LICL+K2B4O7-REVERSIBLE-2KCL+LI2B4O7)+H2O PRI 25-GRADUSACH
    LEPESHKOV, IN
    BODALEVA, NV
    KOTOVA, LT
    ZHURNAL NEORGANICHESKOI KHIMII, 1963, 8 (11): : 2597 - 2602
  • [47] Phase and Physicochemical Properties Diagrams of Quaternary System Li2B4O7 + Na2B4O7 + Mg2B6O11 + H2O
    Wang, Shi-qiang
    Du, Xue-min
    Jing, Yan
    Guo, Ya-fei
    Deng, Tian-long
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (13) : 2503 - 2507
  • [48] Phase and Physicochemical Properties Diagrams of Quaternary System Li2B4O7 + Na2B4O7 + Mg2B6O11 + H2O
    Shi-qiang Wang
    Xue-min Du
    Yan Jing
    Ya-fei Guo
    Tian-long Deng
    Russian Journal of Physical Chemistry A, 2017, 91 : 2503 - 2507
  • [49] Solubilities of Salts in Quaternary System KBr-K2SO4-K2B4O7-H2O and Quinary System KCl-KBr-K2SO4-K2B4O7-H2O at 373 K
    Nie, Guo-Liang
    Sang, Shi-Hua
    Ye, Chao
    Gao, Yun-Yun
    He, Chun-Xia
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (07) : 1372 - 1377
  • [50] Calculations of phase equilibrium parameters of the quaternary systems KBr–K2SO4–K2B4O7–H2O and NaBr–Na2SO4–Na2B4O7–H2O at 298 K
    Rui-Zhi Cui
    Dan Wang
    Yu-Yan Yang
    Shi-Hua Sang
    Russian Journal of Physical Chemistry A, 2017, 91 : 1248 - 1254
12345