Solubility investigations in the systems K2B4O7+Li2B4O7+H2O and Na2B4O7+Li2B4O7+H2O at T=288 K

被引：22
|
作者：
Sang, SH [1 ]
Yin, HA [1 ]
Tang, ML [1 ]
Lei, NF [1 ]
机构：
[1] Chengdu Univ Technol, Dept Appl Chem, Chengdu 610059, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2004年 / 49卷 / 06期
关键词：
D O I：
10.1021/je034280k
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of the salt and the density, electrical conductivity, and pH of ternary systems K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T = 288 K were determined. On the basis of the experimental results, phase diagrams and property composition diagrams were derived. Phase equilibrium solids were Na(2)B(4)O(7)(.)10H(2)O, K(2)B(4)O(7)(.)4H(2)O, and Li(2)B(4)O(7)(.)3H(2)O. Analyses of what was made on the crystallization areas in the phase diagram were discussed. The results of properties in the solution were also discussed simply.
引用
收藏
页码：1586 / 1589
页数：4
相关论文
共 50 条
  • [31] Solid - liquid Equilibria for the Quaternary Na2B4O7-Na2SO4-K2B4O7-K2SO4-H2O System at 323K
    Sang, ShiHua
    Zeng, XiaoXiao
    Ning, HuiYi
    Zhang, Zhenlei
    FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 233-235 : 27 - 31
  • [32] Phase Equilibria in the Ternary Systems KBr–K2B4O7–H2O and KCl–K2B4O7–H2O at 373 K
    CUI Ruizhi
    SANG Shihua
    HU Yongxia
    HU Jiawen
    Acta Geologica Sinica(English Edition), 2013, 87 (06) : 1668 - 1673
  • [33] LIB4O7(NA2B4O7,K2B4O7)-N2H3C2H4OH-H2O SYSTEMS AT 25-DEGREES-C
    SKVORTSOV, VG
    SADETDINOV, SV
    AKIMOV, VM
    MITRASOV, YN
    PETROVA, OV
    KLOPOV, YN
    ZHURNAL NEORGANICHESKOI KHIMII, 1994, 39 (02): : 328 - 332
  • [34] Metastable phase equilibria in the systems K2SO4 + K2B4O7 + H2O and KCl + K2B4O7 + H2O at 308.15 K
    Li, Dong-chan
    Yuan, Jun-sheng
    Wang, Shi-qiang
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (01) : 42 - 46
  • [35] Metastable phase equilibria in the systems K2SO4 + K2B4O7 + H2O and KCl + K2B4O7 + H2O at 308.15 K
    Dong-chan Li
    Jun-sheng Yuan
    Shi-qiang Wang
    Russian Journal of Physical Chemistry A, 2014, 88 : 42 - 46
  • [36] The electronic structure of Li2B4O7(110) and Li2B4O7(100)
    Wooten, D.
    Ketsman, I.
    Xiao, J.
    Losovyj, Ya. B.
    Petrosky, J.
    McClory, J.
    Burak, Ya. V.
    Adamiv, V. T.
    Brown, J. M.
    Dowben, P. A.
    EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2010, 52 (03):
  • [37] 三元体系Li2B4O7-K2B4O7-H2O273K稳定相平衡研究
    张婷婷
    桑世华
    傅超
    王伟
    化学工程, 2017, 45 (03) : 37 - 41
  • [38] Metastable Phase Equilibrium in the Aqueous Quaternary System (Li2SO4 + Na2SO4 + Li2B4O7 + Na2B4O7 + H2O) at 273.15 K
    Zeng, Ying
    Cao, Fujia
    Li, LongGang
    Yu, Xudong
    Lin, Xiaofeng
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05): : 2569 - 2573
  • [39] Solubilities, Densities, and Refractive Indices in the Quaternary System (Li2B4O7 + Na2B4O7 + Mg2B6O11 + H2O) at 298.15 K
    Shi-Qiang Wang
    Yun Song
    Xue-Min Du
    Ya-Fei Guo
    Tian-Long Deng
    Russian Journal of Inorganic Chemistry, 2018, 63 : 116 - 120
  • [40] Solubilities, Densities, and Refractive Indices in the Quaternary System (Li2B4O7 + Na2B4O7 + Mg2B6O11 + H2O) at 298.15 K
    Wang, Shi-Qiang
    Song, Yun
    Du, Xue-Min
    Guo, Ya-Fei
    Deng, Tian-Long
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2018, 63 (01) : 116 - 120
12345