Solubility investigations in the systems K2B4O7+Li2B4O7+H2O and Na2B4O7+Li2B4O7+H2O at T=288 K

被引:22
|
作者
Sang, SH [1 ]
Yin, HA [1 ]
Tang, ML [1 ]
Lei, NF [1 ]
机构
[1] Chengdu Univ Technol, Dept Appl Chem, Chengdu 610059, Peoples R China
来源
关键词
D O I
10.1021/je034280k
中图分类号
O414.1 [热力学];
学科分类号
摘要
The solubility of the salt and the density, electrical conductivity, and pH of ternary systems K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T = 288 K were determined. On the basis of the experimental results, phase diagrams and property composition diagrams were derived. Phase equilibrium solids were Na(2)B(4)O(7)(.)10H(2)O, K(2)B(4)O(7)(.)4H(2)O, and Li(2)B(4)O(7)(.)3H(2)O. Analyses of what was made on the crystallization areas in the phase diagram were discussed. The results of properties in the solution were also discussed simply.
引用
收藏
页码:1586 / 1589
页数:4
相关论文
共 50 条
  • [21] Phase Equilibria in the Ternary Systems KBr-K2B4O7-H2O and KCl-K2B4O7-H2O at 373 K
    Cui Ruizhi
    Sang Shihua
    Hu Yongxia
    Hu Jiawen
    ACTA GEOLOGICA SINICA-ENGLISH EDITION, 2013, 87 (06) : 1668 - 1673
  • [22] Solid-Liquid Stable Equilibria for the Quaternary Na2B4O7-Na2SO4-K2B4O7-K2SO4-H2O System at 288 K
    Sang, Shi Hu
    Li, Heng
    Sun, Ming-Liang
    Peng, Jiang
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05): : 1956 - 1959
  • [23] Liquid-solid equilibrium for quaternary system Na2SO4+K2SO4+Na2B4O7+K2B4O7+H2O at 288K
    Zeng, Y
    Sang, SH
    Li, YQ
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03): : 928 - 931
  • [24] Na2B4O7-K2B4O7-H2O三元体系288K相平衡研究
    桑世华
    唐明林
    殷辉安
    张允湘
    海湖盐与化工, 2002, (01) : 16 - 18
  • [25] Solid-Liquid Phase Equilibria of the Quaternary System (Li2B4O7 + Na2B4O7 + K2B4O7 + H2O) at 323.15 K and Its Application in Industry
    Chen, Lele
    Guo, Yafei
    Deng, Tianlong
    Li, Dan
    Meng, Lingzong
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2020, 65 (05): : 2725 - 2730
  • [26] Metastable Phase Equilibria in the Aqueous Ternary Systems K2B4O7-K2SO4-H2O and K2B4O7-KCl-H2O at 273 K
    Zhang, Tingting
    Yang, Lei
    Zhang, Wenyao
    Sang, Shihua
    Cui, Ruizhi
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2017, 50 (08) : 595 - 600
  • [27] Experimental study of the solubilities of salts in the systems Na2B4O7-NaBr-H2O and Na2B4O7-Na2SO4-NaBr-H2O at 323 K
    Sang, Shi-Hua
    Zhang, Hai
    Zhong, Si-Yao
    Hu, Jia-Wen
    Sun, Ming-Liang
    FLUID PHASE EQUILIBRIA, 2014, 361 : 171 - 174
  • [28] Calculations of phase equilibrium parameters of the quaternary systems KBr-K2SO4-K2B4O7-H2O and NaBr-Na2SO4-Na2B4O7-H2O at 298 K
    Cui, Rui-Zhi
    Wang, Dan
    Yang, Yu-Yan
    Sang, Shi-Hua
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 91 (07) : 1248 - 1254
  • [29] Measurements of the Solid Liquid Equilibria in the Quaternary Systems KBr-K2SO4-K2B4O7-H2O and NaBr-Na2SO4-Na2B4O7-H2O at 298 K
    Cui, Rui-zhi
    Sang, Shi-hua
    Liu, Qing-zhu
    Wang, Pan
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (07): : 2252 - 2257
  • [30] (Liquid plus solid) metastable equilibria in quinary system Li2CO3+Na2CO3+K2CO3+Li2B4O7+Na2B4O7+K2B4O7+H2OatT=288 K for Zhabuye salt lake
    Sang, SH
    Yin, HA
    Tang, ML
    Zhang, YX
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2003, 35 (09): : 1513 - 1520