Solubility investigations in the systems K2B4O7+Li2B4O7+H2O and Na2B4O7+Li2B4O7+H2O at T=288 K

被引：22
|
作者：
Sang, SH [1 ]
Yin, HA [1 ]
Tang, ML [1 ]
Lei, NF [1 ]
机构：
[1] Chengdu Univ Technol, Dept Appl Chem, Chengdu 610059, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2004年 / 49卷 / 06期
关键词：
D O I：
10.1021/je034280k
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The solubility of the salt and the density, electrical conductivity, and pH of ternary systems K2B4O7 + Li2B4O7 + H2O and Na2B4O7 + Li2B4O7 + H2O at T = 288 K were determined. On the basis of the experimental results, phase diagrams and property composition diagrams were derived. Phase equilibrium solids were Na(2)B(4)O(7)(.)10H(2)O, K(2)B(4)O(7)(.)4H(2)O, and Li(2)B(4)O(7)(.)3H(2)O. Analyses of what was made on the crystallization areas in the phase diagram were discussed. The results of properties in the solution were also discussed simply.
引用
收藏
页码：1586 / 1589
页数：4
相关论文
共 50 条
  • [1] Solubility Investigations in the Systems Li2SO4 + Li2B4O7 + H2O and K2SO4 + K2B4O7 + H2O at 288 K
    Sang, Shi-hua
    Zhang, Xiao
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (02): : 808 - 812
  • [2] Metastable Equilibria for the Quaternary System Li2B4O7+Na2B4O7+K2B4O 7K2B4O7+H2O at 15 °C
    Sang Shi-Hua
    Yin Hui-An
    Ni Shi-Jun
    Deng Miao
    CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (10) : 1816 - 1820
  • [3] K2B4O7-Na2B4O7-Li2B4O7-H2O四元体系288K相平衡研究
    桑世华
    唐明林
    殷辉安
    张允湘
    化学工程, 2003, (04) : 68 - 70+6
  • [4] Study on the metastable equilibria of the salt lake brine system Li2SO4+Na2SO4+K2SO4+Li2B4O7+Na2B4O7+K2B4O7+H2O at 288 K
    Zeng, Ying
    Ling, Xiao-Feng
    Ni, Shi-Jun
    Zhang, Cheng-Jiang
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (01): : 164 - 167
  • [5] Phase Equilibria in the Ternary Systems Li2B4O7-MgB4O7-H2O and K2B4O7-MgB4O7-H2O at 273 K
    Fu, Chao
    Sang, Shi-hua
    Zhou, Mei-fang
    Liu, Qing-zhu
    Zhang, Ting-ting
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (03): : 1071 - 1077
  • [6] Metastable equilibrium solubilities of solutions in the quaternary system of K2B4O7-Na2B4O7-Li2B4O7-H2O at 273 K
    Sang Shi-Hua
    Yin Hui-An
    Ni Shi-Jun
    Zhang Cheng-Jiang
    ACTA PHYSICO-CHIMICA SINICA, 2007, 23 (08) : 1285 - 1287
  • [7] Experimental Study on Phase Equilibria in Na2B4O7-Na2SO4-H2O and Li2B4O7-Na2B4O7-H2O Aqueous Ternary Systems at 273 K
    Zhang, Wen Yao
    Li, Xiao Ping
    Yang, Lei
    Sang, Shi Hua
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 93 (06) : 1032 - 1037
  • [8] K2B4O7-Li2B4O7-MgB4O7-H2O四元体系288K相平衡研究
    肖龙军
    桑世华
    赵相颇
    盐业与化工, 2010, 39 (01) : 18 - 20
  • [9] Phase Equilibria of Two Ternary Systems: Li2SO4-Li2B4O7-H2O and K2B4O7-K2SO4-H2O at 273 K
    Yang, Yu-yan
    Zhang, Xue-ping
    Wang, Dan
    Sang, Shi-hua
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2017, 62 (07): : 2123 - 2127
  • [10] K2B4O7-Na2B4O7-Li2B4O7-H2O四元体系273K介稳相平衡
    桑世华
    殷辉安
    倪师军
    张成江
    物理化学学报, 2007, (08) : 1285 - 1287
12345