Thermodynamic properties of ionic liquids in organic solvents from (293.15 to 303.15) K

被引：105

作者：

Pereiro, Ana B. ^{[1
]}

Rodriguez, Ana ^{[1
]}

机构：

[1] Vigo Univ, Dept Chem Engn, Vigo 36210, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2007年 / 52卷 / 02期

关键词：

D O I：

10.1021/je060497d

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Densities, speeds of sound, and refractive indices of the binary mixtures of BMIM PF6 (1-butyl-3-methyl imidazolium hexafluorophosphate), HMIM PF6 (1-hexyl-3-methylimidazolium hexafluorophosphate), OMIM PF6 (1-methyl-3-octylimidazolium hexafluorophosphate), and MMIM CH3SO4 (1,3-dimethylimidazolium methyl sulfate) with 2-butanone, ethylacetate, and 2-propanol were determined from (293.15 to 303.15) K. Excess molar volumes, changes of refractive index on mixing, and deviations in isentropic compressibility were calculated for the above systems. The liquid-liquid equilibrium data of the binary mixtures ionic liquid + 2-propanol were carried out, and they were compared with the correlated values obtained by means of the NRTL and UNIQUAC equations.

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页码：600 / 608

页数：9

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