Physical vapor growth of organic semiconductors

被引:590
作者
Laudise, RA [1 ]
Kloc, C [1 ]
Simpkins, PG [1 ]
Siegrist, T [1 ]
机构
[1] AT&T Bell Labs, Lucent Technol, Murray Hill, NJ 07974 USA
关键词
vapor growth; organic semiconductor; alpha-6T; alpha-4T; alpha-8T; pentacene; anthracene; copper phthalocyanine;
D O I
10.1016/S0022-0248(98)00034-7
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Physical vapor growth in horizontal and vertical systems has been used to grow crystals of a-hexathiophene (alpha-6T), alpha-octithiophene (alpha-8T), alpha-quaterthiophene (alpha-4T), pentacene, anthracene and copper phthalocyanine. Using 10-30 mg of starting material, mm-cm sized crystals, suitable for characterization measurements, have been grown. New polymorphs of alpha-quaterthiophene (high temperature, HT and low temperature, LT) and pentacene were discovered. A horizontal geometry is shown to be advantageous because the fragile crystals are extracted more easily. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:449 / 454
页数:6
相关论文
共 16 条
  • [1] CRYSTAL AND MOLECULAR STRUCTURE OF PENTACENE
    CAMPBELL, RB
    TROTTER, J
    ROBERTSON, JM
    [J]. ACTA CRYSTALLOGRAPHICA, 1961, 14 (07): : 705 - &
  • [2] ORGANIC TRANSISTORS - 2-DIMENSIONAL TRANSPORT AND IMPROVED ELECTRICAL CHARACTERISTICS
    DODABALAPUR, A
    TORSI, L
    KATZ, HE
    [J]. SCIENCE, 1995, 268 (5208) : 270 - 271
  • [3] Growth and structural characterization of the quasi-2D single crystal of alpha-octithiophene
    Fichou, D
    Bachet, B
    Demanze, F
    Billy, I
    Horowitz, G
    Garnier, F
    [J]. ADVANCED MATERIALS, 1996, 8 (06) : 500 - +
  • [4] GARNIER R, 1994, SCIENCE, V264, P1684
  • [5] GUNDLACH DJ, 1997, IEEE DEV, V44, P1325
  • [6] GROWTH AND CHARACTERIZATION OF SEXITHIOPHENE SINGLE-CRYSTALS
    HOROWITZ, G
    BACHET, B
    YASSAR, A
    LANG, P
    DEMANZE, F
    FAVE, JL
    GARNIER, F
    [J]. CHEMISTRY OF MATERIALS, 1995, 7 (07) : 1337 - 1341
  • [7] Karl N., 1980, CRYSTALS GROWTH PROP
  • [8] Physical vapor growth of centimeter-sized crystals of α-hexathiophene
    Kloc, C
    Simpkins, PG
    Siegrist, T
    Laudise, RA
    [J]. JOURNAL OF CRYSTAL GROWTH, 1997, 182 (3-4) : 416 - 427
  • [9] KLOC C, IN PRESS
  • [10] GROWTH OF ALPHA-HEXATHIENYL BY A MICRO MELT TECHNIQUE
    LAUDISE, RA
    BRIDENBAUGH, PM
    SIEGRIST, T
    FLEMING, RM
    KATZ, HE
    LOVINGER, AJ
    [J]. JOURNAL OF CRYSTAL GROWTH, 1995, 152 (03) : 241 - 244