Synthesis of "Clickable" Nano Metal-organic Framework by Generic Postsynthetic Modification Route

被引：13

作者：

Yue, Dan ^{[1
,2
]}

Chen, Dong ^{[1
]}

Zhang, Xin ^{[2
]}

Huang, Yike ^{[2
]}

Wang, Zhenling ^{[1
]}

机构：

[1] Henan Univ Engn, Ctr Anal & Testing, Sch Mat & Chem Engn, Zhengzhou 451191, Henan, Peoples R China

[2] Zhejiang Univ, Sch Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2019年 / 645卷 / 22期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Postsynthetic modification; Porous materials; Nanocrystalline materials; Metal-organic framework; Click chemistry; SELECTIVE DETECTION; TURN-ON; MOF; CHEMISTRY; CU2+;

D O I：

10.1002/zaac.201900225

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Organic azides have been somewhat popularized due to their pivotal role in the emerging field of "click chemistry". A simple approach has been used for the synthesis of uniform nano Fe-MIL-88B-NH2, and a generic postsynthetic modification route has been developed for the synthesis of azide-modified nano Fe-MIL-88B-N-3. The approach also has been used to synthesize the azide-modified IRMOF-3(-N-3). These new azide-modified Fe-MIL-88B-N-3 nanocrystals hold promising potential for the applications in the fields of "click chemistry", nanotechnology devices and nano composite membranes.

引用

页码：1303 / 1306

页数：4

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