Effect of Ionic Liquid Anion Type in the Performance of Solid Polymer Electrolytes Based on Poly(Vinylidene fluoride-trifluoroethylene)

被引：27
|
作者：
Leones, R. [1 ,2 ]
Costa, C. M. [3 ]
Machado, A. V. [4 ]
Esperanca, J. M. S. S. [2 ]
Silva, M. M. [1 ]
Lanceros-Mendez, S. [3 ]
机构：
[1] Univ Minho, Ctr Dept Quim, P-4710057 Braga, Portugal
[2] Univ Nova Lisboa, Inst Tecnol Quim & Biol, P-2780157 Oeiras, Portugal
[3] Univ Minho, Ctr Dept Fis, P-4710057 Braga, Portugal
[4] Univ Minho, IPC, P-4800058 Guimaraes, Portugal
来源：
ELECTROANALYSIS | 2015年 / 27卷 / 02期
关键词：
Battery separator membranes; Porous membranes; Ionic liquid; P(VDF-TrFE); GEL ELECTROLYTES; VISCOSITY; STABILITY; FLUORIDE); MEMBRANES;
D O I：
10.1002/elan.201400530
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The effect of different anions within the ionic liquid in the characteristics of solid polymer electrolytes (SPEs) based on P(VDF-TrFE) has been investigated. 1-ethyl-3-methylimidazolium acetate, [C(2)mim][OAc], 1ethyl- 3-methylimidazolium triflate, [C(2)mim][(CF3SO3)], 1ethyl- 3-methylimidazolium lactate, [C(2)mim][Lactate], 1-ethyl-3-methylimidazolium thiocyanate, [C(2)mim][SNC] and 1-ethyl-3-methylimidazolium hydrogen sulfate [C(2)mim][HSO4] have been used in SPE prepared by solvent casting. The polymer phase, thermal and electrochemical properties of the SPE have been determined. The thermal and electrical properties of the SPEs strongly depend on the selected IL, as determined by their different interactions with the polymer matrix. The room temperature ionic conductivity increases in the following way for the different anions: [SNC]>[CF3SO3)]> [HSO4]>[Lactate]>[OAc], which is mainly dependent on the viscosity of the ionic liquid.
引用
收藏
页码：457 / 464
页数：8
相关论文
共 50 条
  • [1] Development of solid polymer electrolytes based on poly(vinylidene fluoride-trifluoroethylene) and the [N1 1 1 2(OH)][NTf2] ionic liquid for energy storage applications
    Leones, R.
    Costa, C. M.
    Machado, A. V.
    Esperanca, J. M. S. S.
    Silva, M. M.
    Lanceros-Mendez, S.
    SOLID STATE IONICS, 2013, 253 : 143 - 150
  • [2] Effect of ionic liquid on the properties of poly(vinylidene fluoride)-based gel polymer electrolytes
    Dong, Zhen
    Zhang, Qilu
    Yu, Chuhong
    Peng, Jing
    Ma, Jun
    Ju, Xuecheng
    Zhai, Maolin
    IONICS, 2013, 19 (11) : 1587 - 1593
  • [3] Comparing performance of solid polymer electrolytes based on poly(vinylidene fluoride - trifluoroethylene) obtained by different processing techniques
    Costa, C. M.
    Silva, M. M.
    Gomez Ribelles, J. L.
    Lanceros-Mendez, S.
    EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 751 - 752
  • [4] Anomalous piezoelectric properties of poly(vinylidene fluoride-trifluoroethylene)/ionic liquid gels
    Fukagawa, Miki
    Koshiba, Yasuko
    Fukushima, Tatsuya
    Morimoto, Masahiro
    Ishida, Kenji
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2018, 57 (04)
  • [5] Effect of ionic liquid on the properties of poly(vinylidene fluoride)-based gel polymer electrolytes
    Zhen Dong
    Qilu Zhang
    Chuhong Yu
    Jing Peng
    Jun Ma
    Xuecheng Ju
    Maolin Zhai
    Ionics, 2013, 19 : 1587 - 1593
  • [6] Effect of anion type in the performance of ionic liquid/poly(vinylidene fluoride) electromechanical actuators
    Mejri, R.
    Dias, J. C.
    Hentati, S. Besbes
    Martins, M. S.
    Costa, C. M.
    Lanceros-Mendez, S.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2016, 453 : 8 - 15
  • [7] Imprint effect in ferroelectric poly(vinylidene fluoride-trifluoroethylene) thin films
    Zhu, GuoDong
    Luo, XiaoYa
    Zhang, JiHao
    Yan, XueJian
    JOURNAL OF APPLIED PHYSICS, 2009, 106 (07)
  • [8] Electrospun poly(vinylidene fluoride-trifluoroethylene) based flexible magnetoelectric nanofibers
    Hernandez, N.
    Gonzalez-Gonzalez, V. A.
    Dzul-Bautista, I. B.
    Ornelas-Soto, N.
    Barandiaran, J. M.
    Gutierrez, J.
    EUROPEAN POLYMER JOURNAL, 2018, 109 : 336 - 340
  • [9] Modeling of Structure Effect for Ferroelectric Capacitor Based on Poly(vinylidene fluoride-trifluoroethylene) Ultrathin Films
    Li, Long
    Zhang, Xiuli
    Chen, Hongzhen
    Sun, Xiaohui
    Yuan, Haidong
    Xu, Haisheng
    POLYMERS, 2018, 10 (01):
  • [10] High-Performance Room Temperature Lithium-Ion Battery Solid Polymer Electrolytes Based on Poly(vinylidene fluoride-co-hexafluoropropylene) Combining Ionic Liquid and Zeolite
    Barbosa, Joao C.
    Correia, Daniela M.
    Fernandez, Eva M.
    Fidalgo-Marijuan, Arkaitz
    Barandika, Gotzone
    Goncalves, Renato
    Ferdov, Stanislav
    Bermudez, Veronica de Zea
    Costa, Carlos M.
    Lanceros-Mendez, Senentxu
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (41) : 48889 - 48900
12345