Spectroscopic Characterization and In Vitro Antibacterial Activity of Some Novel Metal Complexes With Schiff Base Ligands Derived From Thiosemicarbazide

被引:5
作者
Sakthilatha, D. [1 ]
Deepa, A. [1 ]
Rajavel, R. [1 ]
机构
[1] Periyar Univ, Dept Chem, Salem 636011, Tamil Nadu, India
关键词
Schiff base; thiosemicarbazide; electrochemical; antibacterial studies; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; COPPER(II) COMPLEXES; DERIVATIVES; REACTIVITY; IRON(III); PYRIDINE;
D O I
10.1080/15533174.2013.831880
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Six novel mononuclear Schiff base metal complexes of the type [ML1L2]X and [ML1L2X], where M = Cu(II), Ni(II), Co(II), Mn(II), Zn(II), and VO(IV) have been synthesized by condensation of 1-(1-(pyridine-2-yl)ethylidene)thiosemicarbazide (L-1) and 1-(1-(2,4-dihydroxyphenyl) ethylidene) thiosemicarbazide (L-2) in the presence of divalent metal salts. The synthesized ligands and complexes were structurally characterized on the basis of elemental analysis, IR, UV-visible, H-1 NMR spectroscopy, molar conductance, magnetic susceptibility measurements, and electrochemical studies. The in vitro antibacterial study reveals that the metal complexes inhibit the growth of bacteria more than the free ligands.
引用
收藏
页码:286 / 297
页数:12
相关论文
共 52 条
[1]   A Comparative Study of Chromium(III) Ion-Selective Electrodes Based on N,N-Bis(salicylidene)-o-phenylenediaminatechromium(III) [J].
Abu-Shawish, H. M. ;
Saadeh, S. M. ;
Hartani, K. ;
Dalloul, H. M. .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2009, 6 (04) :729-737
[2]   SYNTHESIS AND CHARACTERIZATION OF THORIUM(IV) AND DIOXOURANIUM(VI) COMPLEXES OF 4-[N(2-HYDROXY-1-NAPHTHALIDENE)AMINO]ANTIPYRINE [J].
AGARWAL, RK ;
PRAKASH, J .
POLYHEDRON, 1991, 10 (20-21) :2399-2403
[3]   Solid state electrical conductivity properties of copper complexes of novel oxime compounds containing oxolane ring [J].
Aydogdu, Y ;
Yakuphanoglu, F ;
Aydogdu, A ;
Tas, E ;
Cukurovali, A .
MATERIALS LETTERS, 2003, 57 (24-25) :3755-3760
[4]   The Electronic Structure of the Vanadyl Ion [J].
Ballhausen, C. J. ;
Gray, Harry B. .
INORGANIC CHEMISTRY, 1962, 1 (01) :111-122
[5]  
Bard AJ, 2001, ELECTROCHEMICAL METH
[6]   Synthesis, characterization, crystal structure and antiproliferative in vitro activity of long-chain aliphatic thiosemicarbazones and their Ni(II) complexes [J].
Belicchi-Ferrari, Marisa ;
Bisceglie, Franco ;
Pelosi, Giorgio ;
Pinelli, Silvana ;
Tarasconi, Pieralberto .
POLYHEDRON, 2007, 26 (17) :5150-5161
[7]   Synthesis, structural characterization, and DFT studies of new mixed-ligand iron(III) Schiff-base complexes [J].
Bhattacharjee, Chira R. ;
Goswami, Pankaj ;
Mondal, Paritosh .
JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (11) :2002-2011
[8]   Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound [J].
Bie, HY ;
Yu, JH ;
Xu, JQ ;
Lu, J ;
Li, Y ;
Cui, XB ;
Zhang, X ;
Sun, YH ;
Pan, LY .
JOURNAL OF MOLECULAR STRUCTURE, 2003, 660 (1-3) :107-112
[9]   Chromium(III), manganese(II), iron(III), cobalt(II), nickel(II) and copper(II) complexes with a pentadentate, 15-membered new macrocyclic ligand [J].
Chandra, S ;
Gupta, K .
TRANSITION METAL CHEMISTRY, 2002, 27 (02) :196-199
[10]  
Cotton F.A., 1999, Advanced Inorganic Chemistry