Synthesis and optical properties of novel double perovskite Ca2MgTeO6:Dy3+,Na+ phosphors for white LEDs

被引:24
作者
Che, Junzhi [1 ]
Deng, Bin [2 ,3 ]
Song, Qinyang [1 ]
Wang, Jianxu [1 ]
Wang, Tao [1 ]
Zhao, Shoucheng [1 ]
Yu, Ruijin [1 ,4 ]
机构
[1] Northwest A&F Univ, Coll Chem & Pharm, Yangling 712100, Shaanxi, Peoples R China
[2] Xiangnan Univ, Coll Chem & Biol & Environm Engn, Chenzhou 423043, Peoples R China
[3] Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423043, Peoples R China
[4] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Peoples R China
关键词
Luminescence; Double perovskite; Ca2MgTeO6; Phosphor; Rare earths; PHOTOLUMINESCENCE PROPERTIES; FLUORESCENT-PROBE; ENERGY-TRANSFER; LUMINESCENCE; DY3+;
D O I
10.1016/j.jre.2020.07.007
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Novel yellow-emitting phosphors of Dy3+-doped double perovskite Ca2MgTeO6 were synthesized by using a conventional high-temperature solid-state reaction. The phase purity, particle morphology, size distribution, elemental composition, luminescence properties, and luminescence decay curves of the resulting products were then analyzed in detail. The Ca2MgTeO6:Dy3+,Na+ phosphors show three emission peaks after near-ultraviolet excitation at 350 nm, which correspond to F-4(9/2) -> H-6(11/2), F-4(9/2) -> H-6(13/2), and F-4(9/2) -> H-6(13/2) transitions, respectively. Among them, the strongest peak is observed at 573 nm. The best doping content of Dy3+ in Ca2MgTeO6:xDy(3+),xNa(+) phosphors is x = 5 mol%. The calculated critical distance of energy transfer between Dy3+ ions is 1.6 nm. Luminescence quenching is confirmed to be due to dipole-dipole interactions among Dy3+ ions. The phosphors show excellent thermal stability with high activation energy (0.27 eV). The Commission Internationale de l'Eclairage (CIE) chromaticity coordinates of the Ca2MgTeO6Dy3+,Na+ phosphors are located in the yellow region. White light-emitting diodes (w-LEDs) were fabricated with a high color rendering index (R-a) of 88 and a good correlated color temperature (CCT) of 5440 K. All observed properties indicate that Ca2MgTeO6:Dy3+,Na+ phosphors have potential applications in display and photonic devices. (C) 2020 Published by Elsevier B.V. on behalf of Chinese Society of Rare Earths.
引用
收藏
页码:634 / 642
页数:9
相关论文
共 44 条
[1]   Synthesis of novel Dy3+ activated Ba2CaZn2Si6O17 phosphors for white light-emitting diodes [J].
Annadurai, G. ;
Kennedy, S. Masilla Moses ;
Sivakumar, V. .
LUMINESCENCE, 2018, 33 (03) :521-527
[2]   TEMPERATURE-DEPENDENT STUDIES OF CATHODOLUMINESCENCE OF GREEN BAND OF ZNO CRYSTALS [J].
BHUSHAN, S ;
CHUKICHEV, MV .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1988, 7 (04) :319-321
[3]   ENERGY TRANSFER IN OXIDIC PHOSPHORS [J].
BLASSE, G .
PHYSICS LETTERS A, 1968, A 28 (06) :444-&
[4]   Synthesis and photoluminescence properties of Ca2LaTaO6:Mn4+ phosphor for plant growth LEDs [J].
Cao, Renping ;
Chen, Tao ;
Ren, Yongchun ;
Chen, Ting ;
Ao, Hi ;
Li, Wensheng ;
Zheng, Guotai .
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 780 :749-755
[5]   Solvothermal synthesis of cesium lead halide nanocrystals with controllable dimensions: a stoichiometry defined growth mechanism [J].
Chen, Min ;
Hu, Huicheng ;
Yao, Nan ;
Yuan, Xiaolei ;
Zhong, Qixuan ;
Cao, Muhan ;
Xu, Yong ;
Zhang, Qiao .
JOURNAL OF MATERIALS CHEMISTRY C, 2019, 7 (46) :14493-14498
[6]   Single-Composition White Light Emission from Dy3+ Doped Sr2CaWO6 [J].
Dai, Yannan ;
Yang, Shuai ;
Shan, Yongkui ;
Duan, Chun-Gang ;
Peng, Hui ;
Yang, Fan ;
Zhao, Qingbiao .
MATERIALS, 2019, 12 (03)
[7]   Vibrational studies and microwave dielectric properties of a-site-substituted tellurium-based double perovskites [J].
Dias, Anderson ;
Subodh, Ganesanpotti ;
Sebastian, Mailadil T. ;
Lage, Marcio M. ;
Moreira, Roberto L. .
CHEMISTRY OF MATERIALS, 2008, 20 (13) :4347-4355
[8]   Controlled synthesis of CeVO4 hierarchical hollow microspheres with tunable hollowness and their efficient photocatalytic activity [J].
Ding, Jinjin ;
Liu, Xuan ;
Wan, Miao ;
Liu, Quan ;
Sun, Tongming ;
Jiang, Guoqing ;
Tang, Yanfeng .
CRYSTENGCOMM, 2018, 20 (31) :4499-4505
[9]   Thermally stable double-perovskite Ca3TeO6: Eu3+ red-emitting phosphors with high color purity [J].
Fan, Feiyue ;
Zhao, Lei ;
Shang, Yifan ;
Liu, Jing ;
Chen, Wenbo ;
Li, Yanyan .
JOURNAL OF LUMINESCENCE, 2019, 211 :14-19
[10]   Ln3+ (Ln = Eu, Dy) - doped Sr2CeO4 fine phosphor particles: Wet chemical preparation, energy transfer and tunable luminescence [J].
Gao, Na ;
Yang, Yanfei ;
Shi, Shikao ;
Wang, Jiye ;
Wang, Shuping ;
Li, Jibiao ;
Fu, Lianshe .
JOURNAL OF RARE EARTHS, 2020, 38 (12) :1273-1280